Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)

被引：15
|
作者：
Shi, YJ
Chen, XT [1 ]
Cai, CX
Zhang, Y
Xue, ZL
You, XZ
Peng, SM
Lee, GH
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA
[3] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan
[4] Nantong Teachers Coll, Dept Chem, Nantong 226007, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 08期
基金：
中国国家自然科学基金;
关键词：
organic-inorganic hybrid; pyrazine; supramolecular structure; hemidirected complex;
D O I：
10.1016/S1387-7003(02)00508-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel 2-D organic-inorganic hybrid compound [(PbBr2)(2) (mu-PyZ)](n) 1, has been prepared, and its X-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2](n) sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：621 / 624
页数：4
相关论文
共 50 条
  • [31] Synthesis, structural characterization and magnetic properties of 2-pyrazinecarboxylate manganese compounds [Mn(pyz)2(H2O)4] and [MnCl(pyz)(H2O)]n (pyz=2-pyrazinecarboxylate)
    Huang, DU
    Zhang, XF
    Chen, CN
    Chen, F
    Liu, QT
    Liao, DZ
    Li, LC
    Sun, LC
    INORGANICA CHIMICA ACTA, 2003, 353 : 284 - 291
  • [32] Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]·2pyz
    M. A. Shestopalov
    A. A. Ivanov
    A. I. Smolentsev
    Yu. V. Mironov
    Journal of Structural Chemistry, 2014, 55 : 139 - 141
  • [33] Magnetic properties of the S=1/2 quasisquare lattice antiferromagnet CuF2(H2O)2(pyz) (pyz = pyrazine) investigated by neutron scattering
    Wang, C. H.
    Lumsden, M. D.
    Fishman, R. S.
    Ehlers, G.
    Hong, T.
    Tian, W.
    Cao, H.
    Podlesnyak, A.
    Dunmars, C.
    Schlueter, J. A.
    Manson, J. L.
    Christianson, A. D.
    PHYSICAL REVIEW B, 2012, 86 (06):
  • [34] Synthesis, structure and magnetic properties of a two-dimensional nickel(II) coordination polymer, {[Ni(pzdc)(pyz)]center dot 2H(2)O}(n) (H(2)pzdc equals pyrazine-2,3-dicarboxylic acid; pyz equals pyrazine)
    Okubo, T
    Kondo, M
    Kawata, S
    Kitagawa, S
    Miyazaki, A
    Enoki, T
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1996, 285 : 437 - 442
  • [35] A twofold interpenetrating network constructed from silver ions coordinated to fumaric acid and pyrazine: Ag2(fum)(H2fum)(pyz)2 (fum = fumarate, pyz = pyrazine)
    Do, Junghwan
    Lee, Yumi
    Kang, Jaeun
    Jacobson, Allan J.
    INORGANICA CHIMICA ACTA, 2012, 382 : 191 - 194
  • [36] Characterization of the Antiferromagnetism in Ag(pyz)2(S2O8) (pyz = Pyrazine) with a Two-Dimensional Square Lattice of Ag2+ Ions
    Manson, Jamie L.
    Stone, Kevin H.
    Southerland, Heather I.
    Lancaster, Tom
    Steele, Andrew J.
    Blundell, Stephen J.
    Pratt, Francis L.
    Baker, Peter J.
    McDonald, Ross D.
    Sengupta, Pinaki
    Singleton, John
    Goddard, Paul A.
    Lee, Changhoon
    Whangbo, Myung-Hwan
    Warter, Michelle M.
    Mielke, Charles H.
    Stephens, Peter W.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (13) : 4590 - +
  • [37] Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]•2pyz
    Shestopalov, M. A.
    Ivanov, A. A.
    Smolentsev, A. I.
    Mironov, Yu. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 55 (01) : 139 - 141
  • [38] Syntheses and Structures of Two New Cu/Nb/pyrazine Complexes: Three Dimensional CuNb(pyz)2OF5 QQ (pyz)(H2O) and Two Dimensional [Cu(pyz)2.5]+[NbF6]- QQ (pyz)
    Halasyamani, R.
    Heier, K. R.
    Willis, M. J.
    Stern, C. L.
    Zeitschrift fuer Anorganische und Allgemeine Chemie, 622 (03):
  • [39] Antiferromagnetism in a Family of S=1 Square Lattice Coordination Polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = Pyrazine)
    Liu, Junjie
    Goddard, Paul A.
    Singleton, John
    Brambleby, Jamie
    Foronda, Francesca
    Moeller, Johannes S.
    Kohama, Yoshimitsu
    Ghannadzadeh, Saman
    Ardavan, Arzhang
    Blundell, Stephen J.
    Lancaster, Tom
    Xiao, Fan
    Williams, Robert C.
    Pratt, Francis L.
    Baker, Peter J.
    Wierschem, Keola
    Lapidus, Saul H.
    Stone, Kevin H.
    Stephens, Peter W.
    Bendix, Jesper
    Woods, Toby J.
    Carreiro, Kimberly E.
    Tran, Hope E.
    Villa, Cecelia J.
    Manson, Jamie L.
    INORGANIC CHEMISTRY, 2016, 55 (07) : 3515 - 3529
  • [40] Antiferromagnetic ordering in a novel five-connected 3D polymer {Cu2(2,5-Me2pyz)[N(CN)2]4}n (2,5-Me2pyz=2,5-dimethylpyrazine)
    Yeung, WF
    Gao, S
    Wong, WT
    Lau, TC
    NEW JOURNAL OF CHEMISTRY, 2002, 26 (05) : 523 - 525
12345