Synthesis and crystal structure of a novel 2-D hybrid compound [(PbBr2)2(μ-Pyz)]n (Pyz = pyrazine)

被引：15

作者：

Shi, YJ

Chen, XT ^{[1
]}

Cai, CX

Zhang, Y

Xue, ZL

You, XZ

Peng, SM

Lee, GH

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

[3] Natl Taiwan Univ, Dept Chem, Taipei 107, Taiwan

[4] Nantong Teachers Coll, Dept Chem, Nantong 226007, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2002年 / 5卷 / 08期

基金：

中国国家自然科学基金;

关键词：

organic-inorganic hybrid; pyrazine; supramolecular structure; hemidirected complex;

D O I：

10.1016/S1387-7003(02)00508-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 2-D organic-inorganic hybrid compound [(PbBr2)(2) (mu-PyZ)](n) 1, has been prepared, and its X-ray structure shows that the supramolecular structure consists of organic-inorganic hybrid layers, each of which is constructed from two [PbBr2](n) sheets and one pyrazine, via Pb-N bonding along the direction of the b-axis, and the divalent lead is penta-coordinated to form a hemidirected complex. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：621 / 624

页数：4

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