Crystal structure of the octahedral cluster complex trans-[{Re6S8}(pyz)4I2]·2pyz

被引：0
|
作者：
M. A. Shestopalov
A. A. Ivanov
A. I. Smolentsev
Yu. V. Mironov
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
来源：
Journal of Structural Chemistry | 2014年 / 55卷
关键词：
rhenium; octahedral chalcogenide clusters; pyrazine; crystal structure;
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学科分类号：
摘要：
The cluster complex of the composition trans-[{Re6S8}(pyz)4I2]· 2pyz (pyz is pyrazine) is obtained by the reaction of Cs4[{Re6S8}I6] with molten pyrazine. The compound crystallizes in the triclinic space group \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$P\bar 1$$\end{document} with the following unit cell parameters: a = 9.0562(7) Å, b = 10.2502(7) Å, c = 12.6783(9) Å, α = 98.537(3)°, β = 107.573(2)°, γ = 106.943(3)°, V = 1036.6(1) Å3, Z = 1, dcalc = 3.377 g/cm3. The crystal structure is built of trans-[{Re6S8}(pyz)4I2] cluster complexes and uncoordinated pyrazine molecules.
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页码：139 / 141
页数：2
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