Reactivity of C,N-Chelated Stannylene with Azobenzene

被引：22

作者：

Padelkova, Zdenka ^{[1
]}

Nechaev, Mikhail S. ^{[2
]}

Lycka, Antonin ^{[3
]}

Holubova, Jana ^{[1
]}

Zevaco, Thomas A. ^{[4
]}

Ruzicka, Ales ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[3] Res Inst Organ Synth VUOS, Pardubice 53218 20, Czech Republic

[4] Forschungszentrum Karlsruhe, Bereich Chem Phys Verfahren, Inst Tech Chem, D-76344 Eggenstein Leopoldshafen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 14期

关键词：

Stannylene; Azobenzene; C-H activation; N ligands; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; UNSATURATED MOLECULES; ALKYNES; ANALOGS; TIN; COMPLEXES; GERMANIUM; COMPOUND; HALIDES;

D O I：

10.1002/ejic.200900181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2058 / 2061

页数：4

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