Reactivity of C,N-Chelated Stannylene with Azobenzene

被引：22

作者：

Padelkova, Zdenka ^{[1
]}

Nechaev, Mikhail S. ^{[2
]}

Lycka, Antonin ^{[3
]}

Holubova, Jana ^{[1
]}

Zevaco, Thomas A. ^{[4
]}

Ruzicka, Ales ^{[1
]}

机构：

[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic

[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[3] Res Inst Organ Synth VUOS, Pardubice 53218 20, Czech Republic

[4] Forschungszentrum Karlsruhe, Bereich Chem Phys Verfahren, Inst Tech Chem, D-76344 Eggenstein Leopoldshafen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 14期

关键词：

Stannylene; Azobenzene; C-H activation; N ligands; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; UNSATURATED MOLECULES; ALKYNES; ANALOGS; TIN; COMPLEXES; GERMANIUM; COMPOUND; HALIDES;

D O I：

10.1002/ejic.200900181

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2058 / 2061

页数：4

共 50 条

[21] Different hydrolytic stabilities of some C,N-chelated germanium alkoxides
Korenkova, M.
Jambor, R.
Ruzickova, Z.
Dostal, L.
INORGANIC CHEMISTRY COMMUNICATIONS, 2016, 69 : 28 - 30
[22] SYNTHETIC APPLICATIONS OF N-CHELATED ORGANOLITHIUM COMPOUNDS
RAUSCH, MD
SARNELLI, AJ
ADVANCES IN CHEMISTRY SERIES, 1974, (130): : 248 - 269
[23] SYNTHETIC APPLICATIONS OF N-CHELATED ORGANOLITHIUM COMPOUNDS
RAUSCH, MD
SARNELLI, AJ
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1972, 164 (AUG-S): : 17 - &
[24] Solvent-Controlled Ring Size in Double C,N-Chelated Stannoxanes
Padelkova, Zdenka
Nechaev, Mikhail S.
Cernosek, Zdenek
Brus, Jiri
Ruzicka, Ales
ORGANOMETALLICS, 2008, 27 (20) : 5303 - 5308
[25] Double-C,N-chelated tri- and diorganotin(IV) fluorides
Novák, P
Brus, J
Císarová, I
Ruzicka, A
Holecek, J
JOURNAL OF FLUORINE CHEMISTRY, 2005, 126 (11-12) : 1531 - 1538
[26] Modular syntheses of chiral and achiral C,N-chelated Pd(II)-pyridinylidenes
Strong, Elizabeth T. J.
Price, Jacquelyn T.
Jones, Nathan D.
DALTON TRANSACTIONS, 2009, (42) : 9123 - 9125
[27] STRUCTURE, PROPERTIES AND COMPARISON OF C,N-CHELATED AND AMIDO-STABILIZED PLUMBYLENES
Bares, Josef
Sourek, Vitezslav
Padelkova, Zdenka
Meunier, Philippe
Pirio, Nadine
Cisarova, Ivana
Ruzicka, Ales
Holecek, Jaroslav
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2010, 75 (01) : 121 - 131
[28] Hydrolysis of C,N-chelated diorganotin(IV) chlorides and catalysis of transesterification reactions
Padelkova, Zdenka
Weidlich, Tomas
Cisarova, Ivana
Ruzicka, Ales
APPLIED ORGANOMETALLIC CHEMISTRY, 2009, 23 (07) : 253 - 257
[29] Oxidative addition of cyanogen bromide to C,N-chelated and Lappert's stannylenes
Svec, Petr
Samsonov, Maksim A.
Ruzickova, Zdenka
Brus, Jiri
Ruzicka, Ales
DALTON TRANSACTIONS, 2021, 50 (16) : 5519 - 5529
[30] Less Is More: Three-Coordinate C,N-Chelated Distannynes and Digermynes
Novak, Miroslav
Bouska, Marek
Dostal, Libor
Ruzicka, Ales
Hoffmann, Alexander
Herres-Pawlis, Sonja
Jambor, Roman
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (21) : 7820 - 7829

← 1 2 3 4 5 →