Reactivity of C,N-Chelated Stannylene with Azobenzene

被引：22
|
作者：
Padelkova, Zdenka [1 ]
Nechaev, Mikhail S. [2 ]
Lycka, Antonin [3 ]
Holubova, Jana [1 ]
Zevaco, Thomas A. [4 ]
Ruzicka, Ales [1 ]
机构：
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Res Inst Organ Synth VUOS, Pardubice 53218 20, Czech Republic
[4] Forschungszentrum Karlsruhe, Bereich Chem Phys Verfahren, Inst Tech Chem, D-76344 Eggenstein Leopoldshafen, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 14期
关键词：
Stannylene; Azobenzene; C-H activation; N ligands; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; UNSATURATED MOLECULES; ALKYNES; ANALOGS; TIN; COMPLEXES; GERMANIUM; COMPOUND; HALIDES;
D O I：
10.1002/ejic.200900181
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：2058 / 2061
页数：4
相关论文
共 50 条
  • [31] Experimental Characterization and Computational Study of Unique C,N-Chelated Lithium Dianions
    Gruver, Jocelyn M.
    West, Scott P.
    Collum, David B.
    Sarpong, Richmond
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (38) : 13212 - 13213
  • [32] Electronic effects on reactivity and anticancer activity by half-sandwich N,N-chelated iridium(III) complexes
    Guo, Lihua
    Zhang, Hairong
    Tian, Meng
    Tian, Zhenzhen
    Xu, Yanjian
    Yang, Yuliang
    Peng, Hongwei
    Liu, Peng
    Liu, Zhe
    NEW JOURNAL OF CHEMISTRY, 2018, 42 (19) : 16183 - 16192
  • [33] The differences in solid state structures of C,N-chelated nbutyltin(IV) fluorides
    Svec, Petr
    Padelkova, Zdenka
    Cernosek, Zdenek
    De Proft, Frank
    Ruzicka, Ales
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (17) : 2937 - 2941
  • [34] SOME MECHANISTIC ASPECTS OF N-CHELATED ORGANOLITHIUM CATALYSIS
    LANGER, AW
    ADVANCES IN CHEMISTRY SERIES, 1974, (130): : 1 - 22
  • [35] C,N-chelated organotin(IV) compounds as catalysts for transesterification and derivatization of dialkyl carbonates
    Weidlich, Tomas
    Dusek, Libor
    Vystrcilova, Barbora
    Eisner, Ales
    Svec, Petr
    Ruzicka, Ales
    APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (06) : 293 - 300
  • [36] Expanding the family of C,N-chelated organotin(IV) pseudohalides: Synthesis and structural characterization
    Svec, Petr
    Ruzickova, Zdenka
    Vlasak, Petr
    Turek, Jan
    De Proft, Frank
    Ruzicka, Ales
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2016, 801 : 14 - 23
  • [37] Opening of boroxines by N,C,N-chelated antimony(III), bismuth(III) and tin(IV) compounds
    Korenkova, Monika
    Mairychova, Barbora
    Jambor, Roman
    Ruzickova, Zdenka
    Dostal, Libor
    INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 47 : 128 - 130
  • [38] POLYMERIZATIONS USING N-CHELATED ALKALI-METAL CATALYSTS
    KAMIENSKI, CW
    ADVANCES IN CHEMISTRY SERIES, 1974, (130): : 163 - 176
  • [39] STEREOCHEMICAL PROPERTIES OF N-CHELATED ALKALI-METAL COMPLEXES
    STUCKY, G
    ADVANCES IN CHEMISTRY SERIES, 1974, (130): : 56 - 112
  • [40] C,N-chelated triorganotin(IV) diesters of 4-ketopimelic acid and their fungicidal activity
    Chalupa, Jan
    Hanlir, Karel
    Padelkova, Zdenka
    Vejsova, Marcela
    Buchta, Vladmir
    Jirasko, Robert
    Ruzicka, Ales
    APPLIED ORGANOMETALLIC CHEMISTRY, 2008, 22 (06) : 308 - 313
12345