Reactivity of C,N-Chelated Stannylene with Azobenzene

被引：22
|
作者：
Padelkova, Zdenka [1 ]
Nechaev, Mikhail S. [2 ]
Lycka, Antonin [3 ]
Holubova, Jana [1 ]
Zevaco, Thomas A. [4 ]
Ruzicka, Ales [1 ]
机构：
[1] Univ Pardubice, Fac Chem Technol, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Res Inst Organ Synth VUOS, Pardubice 53218 20, Czech Republic
[4] Forschungszentrum Karlsruhe, Bereich Chem Phys Verfahren, Inst Tech Chem, D-76344 Eggenstein Leopoldshafen, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 14期
关键词：
Stannylene; Azobenzene; C-H activation; N ligands; MOLECULAR-STRUCTURE; CRYSTAL-STRUCTURE; UNSATURATED MOLECULES; ALKYNES; ANALOGS; TIN; COMPLEXES; GERMANIUM; COMPOUND; HALIDES;
D O I：
10.1002/ejic.200900181
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactivity of a C,N-chelated stannylene L2Sn [L=2-(Me2NCH2)C6H4] with azobenzene yielded two different products. In the case of reaction in diethyl ether at room temperature, the cyclic complex L2Sn-N(Ph)-N(Ph)-SnL2 was isolated. The second compound, isolated from the reaction in boiling THF, is the product of C-H activation and orthometallation of azobenzene, the cyclic [2-(SnL2)-C6H4]-N-N-[C6H4-2-(SnL2)]. Byproducts in the second reaction are the free ligand (LH) and the cyclic complex L2Sn-(L)Sn-Sn(L)(2)-O(H). ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
引用
收藏
页码：2058 / 2061
页数：4
相关论文
共 50 条
  • [1] Reactivity of a C,N-chelated stannylene with chalcogens
    Padelkova, Zdenka
    Cisarova, Ivana
    Nechaev, Mikhail S.
    Ruzicka, Ales
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (18) : 2871 - 2874
  • [2] Unusual Reactivity of a C,N-Chelated Stannylene with Siloxanes and Silanols
    Padelkova, Zdenka
    Svec, Petr
    Kampova, Hana
    Sykora, Jan
    Semler, Miloslav
    Stepnicka, Petr
    Bakardjieva, Snejana
    Willem, Rudolph
    Ruzicka, Ales
    ORGANOMETALLICS, 2013, 32 (08) : 2398 - 2405
  • [3] Reactivity of a C,N-Chelated Stannoxane
    Padelkova, Zdenka
    Vankatova, Hana
    Cisarova, Ivana
    Nechaev, Mikhail S.
    Zevaco, Thomas A.
    Walter, Olaf
    Ruzicka, Aleg
    ORGANOMETALLICS, 2009, 28 (08) : 2629 - 2632
  • [4] New complexes of molybdenum(II) and tungsten(II) with a C,N-chelated stannylene
    Padelkova, Zdenka
    Cisarova, Ivana
    Fejfarova, Karla
    Holubova, Jana
    Ruzicka, Ales
    Holecek, Jaroslav
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2007, 72 (5-6) : 629 - 636
  • [5] Comparison of reactivity of C,N-chelated and Lappert's stannylenes with trimethylsilylazide
    Svec, Petr
    Padelkova, Zdenka
    Alonso, Mercedes
    De Proft, Frank
    Ruzicka, Ales
    CANADIAN JOURNAL OF CHEMISTRY, 2014, 92 (06) : 434 - 440
  • [6] Activation of E-Cl bonds (E = C, Si, Ge and Sn) by a C,N-chelated stannylene
    Padelkova, Zdenka
    Svec, Petr
    Pejchal, Vladimir
    Ruzicka, Ales
    DALTON TRANSACTIONS, 2013, 42 (21) : 7660 - 7671
  • [7] C,C- and C,N-Chelated Organocopper Compounds
    Liu, Liang
    Chen, Hui
    Yang, Zhenqiang
    Wei, Junnian
    Xi, Zhenfeng
    MOLECULES, 2021, 26 (19):
  • [8] P,N-Chelated Gold(III) Complexes: Structure and Reactivity
    Reiersolmoen, Ann Christin
    Battaglia, Stefano
    Orthaber, Andreas
    Lindh, Roland
    Erdelyi, Mate
    Fiksdahl, Anne
    INORGANIC CHEMISTRY, 2021, 60 (05) : 2847 - 2855
  • [9] Structure of N,C,N-chelated organotin(IV) fluorides
    Novak, Petr
    Cisarova, Ivana
    Kolarova, Lenka
    Ruzicka, Ales
    Holecek, Jaroslav
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2007, 692 (20) : 4287 - 4296
  • [10] Reduction of C,N-chelated Diorganotin(IV) Dichlorides
    Turek, Jan
    Padelkova, Zdenka
    Nechaev, Mikhail S.
    Ruzicka, Ales
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2010, 695 (15-16) : 1843 - 1847
12345