3-Methyl-1-(1-phenylethyl)pyridinium bis(1,2-dicyanoethene-1,2-dithiolato)-nickelate(III)

被引：0
|
作者：
Ni, Chun-Lin [1 ]
Liu, Ming-Guo
机构：
[1] China Three Gorges Univ, Coll Chem & Life Sci, Hubei 443002, Yichang, Peoples R China
[2] S China Agr Univ, Coll Sci, Ctr Inorgan Funct Mat, Dept Appl Chem, Guangzhou 510642, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806025281
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new ion-pair complex, (C14H16N)[Ni(C4N2S2)(2)] or (PhEtPyMe)(+)[Ni(mnt)(2)](-) [(PhEtPyMe)(+) is 1-(1-phenylethyl)-3- methylpyridinium and mnt(2-) is maleonitriledithiolate], crystallizing with two anions and two cations in the asymmetric unit, has been synthesized. The Ni-III atoms exhibit square-planar coordination geometry with four S atoms from two mnt(2-) ligands. The cations and anions form well segregated columnar stacks along the a axis. Weak Ni center dot center dot center dot S, S center dot center dot S and pi-pi interactions between anions mediate the formation of one-dimensional zigzag chains of Ni-III ions.
引用
下载
收藏
页码：M1751 / M1753
页数：3
相关论文
共 50 条
  • [41] TETRATHIAFULVALINIUM BIS-CIS-(1,2-PERFLUOROMETHYLETHYLENE-1,2-DITHIOLATO)PLATINUM
    KASPER, JS
    INTERRANTE, LV
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (OCT15): : 2914 - 2916
  • [42] Mixed-ligand complexes of technetiums .16. Synthesis and structure of (1,2-dicyanoethene-1,2-dithiolato)bis(dimethylphenylphosphine)nitridotechnetium(V), [TcN(Me(2)PhP)(2)(mnt)]
    Ritter, S
    Abram, U
    Dilworth, JR
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (11): : 1975 - 1978
  • [43] Bis[2-(4-bromobenzyl)isoquinolinium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(II)
    Zhou, Ai-Qun
    Zhou, Jia-Rong
    Ni, Chun-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2980 - U1093
  • [44] Bis[1-(4-fluorobenzyl)pyridinium]bis(2,2-dicyanoethene-1,1-dithiolato-κ2S,S′)nickelate(II)
    Zhou, Ai-Qun
    Ni, Chun-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M3084 - U2027
  • [45] Bis[4-(dimethylamino)pyridinium] bis(1,2-dicyanoethene1,2-dithiolato-κ2S, S′)cuprate(II)
    Zhou, H
    Ren, XM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1119 - M1121
  • [46] catena-Poly[[[acetonitrilebis[μ-bis(diphenylphosphino)-methane-κ2 P:P′]dicopper(I)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)-tungstate(IV)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]
    Fu, Wei-Wei
    Chen, Zhong-Ning
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M482 - M483
  • [47] Bis(diethylenetriamine-k3N,N′,N")nickel(II)bis(1,2-dicyanoethene-1,2-dithiolato-k2S,S′)nickel(II)
    Zhang, Dao-Peng
    Wang, Hai-Long
    Zhang, Li-Fang
    Ni, Zhong-Hai
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1264 - U464
  • [48] REACTION OF BIS-(1,2-DIPHENYLETHYLENE-1,2-DITHIOLATO)NICKEL WITH CUMENE HYDROPEROXIDE
    HRONEC, M
    MALIK, L
    STASKO, A
    JOURNAL OF MOLECULAR CATALYSIS, 1985, 30 (1-2): : 251 - 258
  • [49] 2-amino-1-(4-fluorobenzyl)pyridinium bis(1,2-di-cyanoethane-1,2-dithiolato-κ2S,S′)nickelate(III)
    Ni, Chun-Lin
    Zhou, Jia-Rong
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M959 - M961
  • [50] Bis[4-(dimethylamino)pyridinium] bis(1,2-dicyanoethylene-1,2-dithiolato-κ2S,S′)nickelate(II)
    Zhou, Jia-Rong
    Hou, Yong
    Ni, Chun-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2030 - U92
12345