catena-Poly[[[acetonitrilebis[μ-bis(diphenylphosphino)-methane-κ2 P:P′]dicopper(I)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)-[(1,2-dicyanoethylene-1,2-dithiolato)-tungstate(IV)]-μ-(1,2-dicyanoethylene-1,2-dithiolato)] diethyl ether disolvate acetonitrile solvate]

被引：1

作者：

Fu, Wei-Wei

Chen, Zhong-Ning ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807000979

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The reaction between [Cu-2(mu-bis(diphenylphosphino)methane)(2)(MeCN)(2)](ClO4)(2) and (Bu4N)(2)[W(cis-1,2-dicyanoethylene-1,2-dithiolate)(3)] gave the title compound, {[Cu2W(C4N2S2)(3)(C2H3N)(C25H22P2)(2)]center dot 2C(4)H(10)O center dot C2H3N}(n). Due to the binding between a Cu atom of the binuclear copper unit [Cu-2{bis(diphenylphosphino)methane}(2)(MeCN)](2+) and the N atoms of the buliding block [W(cis-1,2-dicyano-ethylene-1,2-dithiolate)(3)](2-), a one-dimensional zigzag chain structure is formed.

引用

页码：M482 / M483

页数：2

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