3-Methyl-1-(1-phenylethyl)pyridinium bis(1,2-dicyanoethene-1,2-dithiolato)-nickelate(III)

被引：0
|
作者：
Ni, Chun-Lin [1 ]
Liu, Ming-Guo
机构：
[1] China Three Gorges Univ, Coll Chem & Life Sci, Hubei 443002, Yichang, Peoples R China
[2] S China Agr Univ, Coll Sci, Ctr Inorgan Funct Mat, Dept Appl Chem, Guangzhou 510642, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806025281
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new ion-pair complex, (C14H16N)[Ni(C4N2S2)(2)] or (PhEtPyMe)(+)[Ni(mnt)(2)](-) [(PhEtPyMe)(+) is 1-(1-phenylethyl)-3- methylpyridinium and mnt(2-) is maleonitriledithiolate], crystallizing with two anions and two cations in the asymmetric unit, has been synthesized. The Ni-III atoms exhibit square-planar coordination geometry with four S atoms from two mnt(2-) ligands. The cations and anions form well segregated columnar stacks along the a axis. Weak Ni center dot center dot center dot S, S center dot center dot S and pi-pi interactions between anions mediate the formation of one-dimensional zigzag chains of Ni-III ions.
引用
下载
收藏
页码：M1751 / M1753
页数：3
相关论文
共 50 条
  • [21] Bis[1-(4-bromobenzyl)-3-methylpyrazinium] bis(1,2-dicyanoethene-1,2-dithiolato-κ3S, S′)-nickelate(II)
    Ni, CL
    Liu, MG
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : M767 - M769
  • [22] β-phase of 1-(4-bromobenzyl)pyridinium bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)platinate(III)
    Chen, YC
    Ren, XM
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2176 - M2178
  • [23] CRYSTAL STRUCTURE OF TRIPHENYLMETHYLPHOSPHONIUM BIS(1,2-DICYANOETHYLENE-1,2-DITHIOLATO)NICKELATE(3)
    FRITCHIE, CJ
    ACTA CRYSTALLOGRAPHICA, 1966, 20 : 107 - &
  • [24] 3-Butyl-1-methyl-1H-imidazol-3-ium bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(III)
    Yu, Shan-Shan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1726 - U1034
  • [25] Bis(4-dimethylamino-1-ethylpyridinium)bis(1,2-dicyanoethene-1,2-dithiolato-kappa S-2,S')nickelate(II)
    Yu, Shan-Shan
    Zhou, Hong
    Ren, Xiao-Ming
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : M395 - +
  • [26] 1-(4-bromobenzyl)pyridinium bis(1,2-dicyanoethylene-1,2-dithiolato) cuprate(III)
    Xu, H.
    Ren, X. -M.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M3134 - M3136
  • [27] Bis(1-ethyl-4,4'-bipyridin-1-ium) bis(1,2-dicyanoethene-1,2-dithiolato-kappa S-2,S')-nickelate(II)
    Chen, Yao
    Ning, Wei-Hua
    Liu, Jian-Lan
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M428 - +
  • [28] Bis[(3-fluorobenzyl)triphenylphosphonium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(II)
    Liao, Quan-Bin
    Liu, Ming-Guo
    Ni, Chun-Lin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2858 - U2099
  • [29] Bis(4-cyano-1-methylpyridinium) bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)cuprate(II)
    Wang, Na
    Wang, Jin-Guo
    Min, An-Jie
    Fu, Yao-Wen
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M164 - U794
  • [30] 1-(4-Iodobenzyl)-3-methylpyridinium bis(benzene-1,2-dithiolato)nickelate(III)
    Liu, Guang-Xiang
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : M1607 - +
12345