Few-layer MoS2 nanosheets incorporated into hierarchical porous carbon for lithium-ion batteries

被引:68
|
作者
Wang, Haiyan [1 ]
Ren, Dayong [1 ]
Zhu, Zhengju [1 ]
Saha, Petr [2 ]
Jiang, Hao [1 ]
Li, Chunzhong [1 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Key Lab Ultrafine Mat, Minist Educ, Shanghai 200237, Peoples R China
[2] Tomas Bata Univ, Univ Inst, Ctr Polymer Syst, Trida T Bati 5678, Zlin 76001, Czech Republic
基金
中国国家自然科学基金;
关键词
Few-layer MoS2; Biomass; Hierarchical porous carbon; Lithium ion batteries; EXCELLENT ELECTROCHEMICAL PERFORMANCE; COMPOSITES; NANOCOMPOSITES; MONOLAYER; EFFICIENT; TEMPLATE; GROWTH;
D O I
10.1016/j.cej.2015.11.105
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In order to overcome the serious stacking and poor conductivity of graphene-like MoS2 nanosheets, we have developed the synthesis of few-layer MoS2 nanosheets incorporated into biomass -derived hierarchical porous carbon frameworks (labeled as MoS2/C hybrids) utilizing the strong water-absorbing power of auricularia from its inherent rich porous structure. The as-obtained MoS2/C hybrids, when applied as lithium-ion batteries anode materials, show an improved specific capacity of 707.4 mA h(-1) compared with the commercial MoS2 nanosheets (580.2 mA h g(-1)) and the corresponding hierarchical porous carbon (215.5 mA h g(-1)). More meaningfully, they possess an impressive cycle life, almost without capacity fading even after 500 cycles at 1600 mA g(-1). The intriguing performance is mainly attributed to the well-dispersion of few-layer MoS2 nanosheets into hierarchical porous carbon. We believe this work will provide a new insight on the design and synthesis of novel carbon-based electrode materials for potential applications in lithium-ion batteries and other clean energy devices. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:179 / 184
页数:6
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