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Novel plasma-engineered MoS2 nanosheets for superior lithium-ion batteries
被引:45
|作者:
Liu, Yanyan
[1
]
Zhang, Long
[1
]
Zhao, Yuanchun
[1
]
Shen, Tongde
[1
]
Yan, Xinlin
[2
]
Yu, Chuang
[3
]
Wang, Hongqiang
[4
]
Zeng, Hong
[5
]
机构:
[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Hebei, Peoples R China
[2] Vienna Univ Technol, Inst Solid State Phys, Wiedner Hauptstr 8-10, A-1040 Vienna, Austria
[3] Delft Univ Technol, Dept Radiat Sci & Technol, Mekelweg 15, NL-2629 JB Delft, Netherlands
[4] Hebei Univ, Coll Chem & Environm Sci, Baoding 071000, Hebei, Peoples R China
[5] China Iron & Steel Res Inst Grp, Advance Technol & Mat Co Ltd, Beijing Key Lab Energy Nanomat, Beijing 100081, Peoples R China
关键词:
MoS2;
Oxygen plasma;
O doping;
Imperfections;
Lithium-ion batteries;
HYDROGEN EVOLUTION;
MOLYBDENUM-DISULFIDE;
ULTRATHIN NANOSHEETS;
EFFICIENT ELECTROCATALYST;
GRAPHENE OXIDE;
ANODE MATERIAL;
LAYER MOS2;
CARBON;
PERFORMANCE;
BONDS;
D O I:
10.1016/j.jallcom.2019.02.156
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
It is a highly relevant topic concerning how to improve the electrochemical performance of anode materials for the next generation lithium-ion batteries (LIBs). Herein, for the first time, we report a facile and controllable approach to modify MoS2 nanosheets, a typical 2D material, as an anode material for advanced LIBs via oxygen plasma engineering. An oxygen plasma treatment not only generates vacancies/defects but also incorporates heteroatom doping to form Mo-O-C bonds. This unique hybrid specialty enables the oxygen-plasma-treated MoS2 to achieve superior electrochemical performance with high reversible capacities, a long-term cycle life, and good rate capabilities. The plasma-assisted modification is believed to be applicable for other 2D materials as an efficient anode for energy storages. (C) 2019 Elsevier B.V. All rights reserved.
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页码:996 / 1003
页数:8
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