An (8,3)-a 3D coordination network and concomitant three-connected supramolecular isomers

被引：22

作者：

Luisi, Brian S.

Kravtsov, Victor Ch.

Moulton, Brian D. ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02906 USA

[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 10期

关键词：

D O I：

10.1021/cg060534x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu-2(tae)(bipy)(2)]center dot 2NO(3)(-)center dot xS (bipy) 4,4'-bipyridine; tae = dibasic tetraacetylethane; S = solvent: H2O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.

引用

页码：2207 / 2209

页数：3

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