Two novel nanoporous supramolecular architectures based on copper(I) coordination polymers with uniform (8,3) and (8210) nets:: In situ formation of tetrazolate ligands

被引:176
|
作者
Wu, T [1 ]
Yi, BH [1 ]
Li, D [1 ]
机构
[1] Shantou Univ, Dept Chem, Guangdong 515063, Peoples R China
关键词
D O I
10.1021/ic050063o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The hydro/solvothermal reactions of Cu(I)/Cu(II) salt, NaN3, and acetonitrile in water or methanol yield two noninterpenetrated supramolecular networks containing 1D hexagonal and square nanochannels, {[Cu(Mtta)]center dot 0.17H(2)O}(n) (1) and its pseudopolymorph [Cu(Mtta)](n) (2) (Mtta = 5-methyl tetrazolate), involving ligand in-situ formation by cycloaddition of nitriles and azides. The copper(1) centers in both complexes are all bridged by Mtta ligands, forming the different shapes of the cavity. 1 exhibits an unprecedented uniform (8, 3) topological metal network, whereas 2 is a 3-connected (8(2)10) metal net.
引用
收藏
页码:4130 / 4132
页数:3
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