An (8,3)-a 3D coordination network and concomitant three-connected supramolecular isomers

被引:22
|
作者
Luisi, Brian S.
Kravtsov, Victor Ch.
Moulton, Brian D. [1 ]
机构
[1] Brown Univ, Dept Chem, Providence, RI 02906 USA
[2] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
关键词
D O I
10.1021/cg060534x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An unprecedented (8,3)-a 3D coordination network was synthesized using crystal engineering strategies as one of three concomitant supramolecular isomers of the general formula [Cu-2(tae)(bipy)(2)]center dot 2NO(3)(-)center dot xS (bipy) 4,4'-bipyridine; tae = dibasic tetraacetylethane; S = solvent: H2O/MeOH). The (8,3)-a network yields optically active single crystals with 58% solvent-accessible volume, despite 4-fold interpenetration.
引用
收藏
页码:2207 / 2209
页数:3
相关论文
共 50 条
  • [21] Synthesis, Structure and Electric Property of a 3D Supramolecular CoⅡ Coordination Complex
    沈伟
    肖勋文
    叶芬霞
    王明军
    温一航
    ChineseJournalofStructuralChemistry, 2018, 37 (11) : 1829 - 1833
  • [22] Synthesis, structure and properties of a nickel coordination polymer with 3D supramolecular framework
    Li, Fu-An
    Yang, Wei-Chun
    Li, Song-Tian
    Miao, Xu
    INORGANIC AND NANO-METAL CHEMISTRY, 2017, 47 (03) : 433 - 437
  • [23] Synthesis, Structure and Photoelectric Property of a 3D Supramolecular Zinc Coordination Polymer
    Luo Ya-Nan
    Liu Zhi-Chen
    Jiang Hui-Yang
    Yu Li-Yang
    Yu Xiao-Yang
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 37 (03) : 421 - 426
  • [24] Two ligand-length-tunable interpenetrating coordination networks with stable Zn2 unit as three-connected uninode and supramolecular topologies
    Xu, Guohai
    Lv, Jianyi
    Guo, Peng
    Zhou, Zhonggao
    Du, Ziyi
    Xie, Yongrong
    CRYSTENGCOMM, 2013, 15 (22): : 4473 - 4482
  • [25] A noninterpenetrating 3D coordination network with rare (4,6)-connected (4.53.62)2(42.56.64.83) topology
    Xue, Lin
    Luo, Feng
    Che, Yun-xia
    Zheng, Ji-min
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 832 (1-3) : 132 - 137
  • [26] A Coordination Polymer With a (3,4)-Connected (62.8)2(62.84) 3D Network: Synthesis, Crystal Structure and Luminescent Properties
    Liu, Guang-Xiang
    Guo, Wei
    Nishihara, Sadafumi
    Ren, Xiao-Ming
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (09) : 1222 - 1226
  • [27] Hydrogen Bonded 3D Supramolecular Architectures of Three Saccharinate Salts
    Shouwen Jin
    Daqi Wang
    Journal of Chemical Crystallography, 2011, 41 : 1085 - 1092
  • [28] Hydrogen Bonded 3D Supramolecular Architectures of Three Saccharinate Salts
    Jin, Shouwen
    Wang, Daqi
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (07) : 1085 - 1092
  • [29] Compressed Cesium Polyhydrides: Cs+ Sublattices and H3- Three-Connected Nets
    Shamp, Andrew
    Hooper, James
    Zurek, Eva
    INORGANIC CHEMISTRY, 2012, 51 (17) : 9333 - 9342
  • [30] A 3D Robust and Microporous B←N Framework with 8-connected Sandwich Nodes for Efficient Separation of Hexane Isomers
    Lin, Hongyu
    Zhang, Hao
    Li, Yunbin
    Yuan, Furong
    Zheng, Xiaoqing
    He, Lei
    Li, Lu
    Zhang, Yongfan
    Xiang, Shengchang
    Chen, Banglin
    Zhang, Zhangjing
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2025, 64 (04)