Enantioselective synthesis of C1-C4 and C5-C14 fragments of cytospolide D

被引：0
|
作者：
Kaur, Amanpreet [1 ]
Gehlawat, Anju [1 ]
Prakash, Ranjana [1 ]
Pandey, Satyendra Kumar [1 ,2 ]
机构：
[1] Thapar Inst Engn & Technol, Sch Chem & Biochem, Patiala 147001, Punjab, India
[2] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
ARKIVOC | 2021年
关键词：
Cytospolide; Sharpless AD; MacMillan's crossed aldol; Mitsunobu inversion; Yamaguchi esterification; HOMOLOGATED ALLYLIC ALCOHOLS; ASYMMETRIC DIHYDROXYLATION; ENDOPHYTIC FUNGUS; LIGAND CLASS; CONVERSION; EPOXIDES; ROUTE; CORE;
D O I：
10.24820/ark.5550190.p011.648
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convergent approach for the synthesis of the two key fragments (C1-C4 and C5-C14) of cytospolide D is described. Key transformations include MacMillan's crossed aldol, Sharpless asymmetric dihydroxylation (AD) and Mitsunobu inversion reactions. [GRAPHICS] .
引用
收藏
页码：158 / 170
页数：13
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