Enantioselective synthesis of C1-C4 and C5-C14 fragments of cytospolide D

被引：0

作者：

Kaur, Amanpreet ^{[1
]}

Gehlawat, Anju ^{[1
]}

Prakash, Ranjana ^{[1
]}

Pandey, Satyendra Kumar ^{[1
,2
]}

机构：

[1] Thapar Inst Engn & Technol, Sch Chem & Biochem, Patiala 147001, Punjab, India

[2] Banaras Hindu Univ, Inst Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India

来源：

ARKIVOC | 2021年

关键词：

Cytospolide; Sharpless AD; MacMillan's crossed aldol; Mitsunobu inversion; Yamaguchi esterification; HOMOLOGATED ALLYLIC ALCOHOLS; ASYMMETRIC DIHYDROXYLATION; ENDOPHYTIC FUNGUS; LIGAND CLASS; CONVERSION; EPOXIDES; ROUTE; CORE;

D O I：

10.24820/ark.5550190.p011.648

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convergent approach for the synthesis of the two key fragments (C1-C4 and C5-C14) of cytospolide D is described. Key transformations include MacMillan's crossed aldol, Sharpless asymmetric dihydroxylation (AD) and Mitsunobu inversion reactions. [GRAPHICS] .

引用

页码：158 / 170

页数：13

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