Synthesis and crystal structure of 1,3-bis(5-formylpyrrol-2-yl)benzene and its conversion to a macrocyclic derivative

被引：0

作者：

Sener, M. Kasim

Sanchez-Garcia, David

Akkurt, Mehmet

Yildirim, Sema Ozturk

Fun, Hoong-Kun

Sessler, Jonathan L. ^{[1
]}

机构：

[1] Yuzuncii Yil Univ, Dept Chem, TR-65080 Van, Turkey

[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[4] Erciyes Univ, Dept Phys, TR-38039 Kayseri, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 02期

关键词：

Schiff base; bisformylpyrrole; macrocycle; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13 C NMR, and 1 H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P2(1)/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) angstrom, beta = 105.892(2) degrees, V = 1291.00(9) angstrom(3), and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.

引用

页码：243 / 251

页数：9

共 50 条

[41] 1,3-BIS(4-ETHYNYLBENZOYL)BENZENE - SYNTHESIS AND POLYMERIZATION
LUCOTTE, G
DELFORT, B
POLYMER BULLETIN, 1991, 26 (01) : 7 - 13
[42] 1,3-Bis[(3-allylimidazol-3-ium-1-yl)methyl]benzene bis(hexafluoridophosphate)
Haque, Rosenani A.
Ghdhayeb, Mohammed Z.
Abdallah, Hassan H.
Quah, Ching Kheng
Fun, Hoong-Kun
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O80 - U2047
[43] An efficient synthesis of 1,3-bis(1,4,7-triazacyclonon-1-yl)-2-hydroxypropane, [1,3-bis(TACN)-2-propanol]
Florio, P.
Campi, E. M.
Potdar, M. K.
Jackson, W. R.
Hearn, M. T. W.
GREEN CHEMISTRY LETTERS AND REVIEWS, 2012, 5 (03) : 251 - 254
[44] Synthesis, characterization and computational studies of 1,3-bis[(E)-furan-2-yl)methylene]urea and 1,3-bis[(E)-furan-2-yl)methylene]thiourea
Alabi, Kazeem Adelani
Abdulsalami, Ibrahim Olasegun
Adeoye, Moriam Dasola
Aderinto, Shukurat Modupe
Adigun, Rasheed Adewale
PHYSICAL SCIENCES REVIEWS, 2022, 7 (08) : 923 - 931
[45] Crystal structure of (E)-1,3-bis(6-methoxynaphthalen-2-yl)prop-2-en-1-one
Patel, Paresh N.
Chadha, Anju
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : O884 - U600
[46] Synthesis, crystal structure and DNA binding studies of Zn(II) complex with 1,3-bis(benzimidazol-2-yl)-2-oxapropane
Zhou, QH
Yang, P
ACTA CHIMICA SINICA, 2006, 64 (08) : 793 - 798
[47] SYNTHESIS, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF 2-DICYANOMETHYLENE-1,3-BIS(FERROCENYLMETHYL)-1,3-DIAZOLIDINE
BENITO, A
CANO, J
MARTINEZMANEZ, R
PAYA, J
SOTO, J
JULVE, M
LLORET, F
MARCOS, MD
SINN, E
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (13): : 1999 - 2003
[48] Synthesis and crystal structure of discrete complexes and coordination polymers containing 1,3-bis(pyrazol-1-yl)propane ligands
Potapov, Andrei S.
Domina, Galina A.
Petrenko, Tatiana V.
Khlebnikov, Andrei I.
POLYHEDRON, 2012, 33 (01) : 150 - 157
[49] Synthesis, crystal structure and photophysical properties of 1,4-bis(1,3-diazaazulen-2-yl)benzene: a new π building block
Sun, Peili
Zhang, Zongyao
Luo, Hongxia
Zhang, Pu
Qin, Yujun
Guo, Zhi-Xin
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2018, 74 : 171 - +
[50] Crystal structure of bis[1,3-bis(benzimidazol-2-yl)benzene]dichlorocadmium(II), Cd(C20H14N4)2Cl2
Jiang, Bing-Li
Meng, Fa-Yan
Wang, Li
Lin, Cui-Wu
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (02): : 313 - 314

← 1 2 3 4 5 →