Synthesis and crystal structure of 1,3-bis(5-formylpyrrol-2-yl)benzene and its conversion to a macrocyclic derivative

被引：0
|
作者：
Sener, M. Kasim
Sanchez-Garcia, David
Akkurt, Mehmet
Yildirim, Sema Ozturk
Fun, Hoong-Kun
Sessler, Jonathan L. [1 ]
机构：
[1] Yuzuncii Yil Univ, Dept Chem, TR-65080 Van, Turkey
[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
[3] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia
[4] Erciyes Univ, Dept Phys, TR-38039 Kayseri, Turkey
来源：
TURKISH JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 02期
关键词：
Schiff base; bisformylpyrrole; macrocycle; crystal structure;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This report details the synthesis and characterization of a new diformyl pyrrole derivative 2 and its macrocyclic derivative 3. The new compounds were characterized by FT-IR, 13 C NMR, and 1 H NMR spectroscopies and via mass spectrometric analysis. The structure of 2 in the solid state was determined using X-ray diffraction methods (monoclinic, P2(1)/c, a = 17.3760(7), b = 4.9719(2), c = 15.5374(5) angstrom, beta = 105.892(2) degrees, V = 1291.00(9) angstrom(3), and Z = 4). The molecular structure is stabilized by N-H...O and C-H...O intermolecular hydrogen bonds. The present bisformylpyrrole derivative 2 provides a new precursor that may be useful in the synthesis of new, functional macrocyclic systems.
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收藏
页码：243 / 251
页数：9
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