Rhodium(III)-Catalyzed Redox-Neutral C-H Arylation via Rearomatization

被引：44
|
作者：
Zhang, Xueyun [1 ,2 ]
Wang, Fen [1 ]
Qi, Zisong [1 ]
Yu, Songjie [1 ]
Li, Xingwei [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
[2] Qilu Univ Technol, Sch Chem & Pharmaceutial Engn, Jinan 250353, Peoples R China
来源：
ORGANIC LETTERS | 2014年 / 16卷 / 06期
关键词：
BOND FORMATION; CATALYZED ANNULATION; CONJUGATE ADDITION; FACILE SYNTHESIS; BORONIC ACIDS; EASY ROUTE; ACTIVATION; RHODIUM; ARENES; FUNCTIONALIZATION;
D O I：
10.1021/ol500186j
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Rhodium(III)-catalyzed arylation of arenes bearing a chelating group has been realized via a redox-economy process using 4-hydroxycyclohexa-2,5-dienones as the arylating reagents, leading to the synthesis of 3-arylated phenols. This redox-neutral process proceeds via a C-H activation pathway with rearomatization being the driving force.
引用
收藏
页码：1586 / 1589
页数：4
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