One-Pot Synthesis of Thiocarbamide Esters: Construction of C-S Bonds under Transition-Metal-Free Conditions

被引：0

作者：

Deng, Shi-Hao ^{[1
]}

Yu, Jun-Xia ^{[1
]}

Xiao, Hua-Qing ^{[5
]}

Dong, Zhi-Bing ^{[1
,2
,3
,4
]}

机构：

[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China

[2] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China

[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China

[4] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China

[5] Hubei Greenhome Mat Technol, Xiantao 433000, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 46期

关键词：

C-S bond; One-Pot; Synthesis; Transition-Metal free; Thiocarbamide Esters; ARYLBORONIC ACIDS; THIOETHERS; CHLORIDES; DIARYL; THIOLS;

D O I：

10.1002/ejoc.202201167

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient and effective method for the construction of C-S bond under transition-metal free conditions was reported. Thus, diverse thiocarbamide esters could be smoothly obtained in moderate to good yields from inexpensive and readily available starting materials, such as phenyl isothiocyanate, alcohols and benzyl halides. This method features mild conditions, easy operation, short reaction time and broad substrate scopes, providing a facile and convenient strategy for the preparation of some compounds with potential biological activities.

引用

页数：4

共 50 条

[41] One-Pot Synthesis of Quinoxalines Starting from Aldehydes Under Metal-Free Conditions
Hu, Zhong-Yuan
Du, Ding
Tang, Wei-Fang
Lu, Tao
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (05) : 2262 - 2264
[42] One-Pot Transition-Metal-Free Synthesis of Polysubstituted Fused Benzene Derivatives from Methyl Enol Ethers and Alkynes
Ahmad, Sarwat Asma Ziya
Khan, Faiz Ahmed
CHEMISTRYSELECT, 2022, 7 (33):
[43] One-pot facile and mild construction of densely functionalized pyrimidines in water via consecutive C-C and C-S bonds formation
Sahu, Pramod K.
Sahu, Praveen K.
Kaurav, Manvendra S.
Messali, Mouslim
Almutairi, Saud M.
Sahu, Puran L.
Agarwal, Dau D.
RSC ADVANCES, 2018, 8 (59): : 33952 - 33959
[44] Transition-Metal-Free Coupling Reaction of Dithiocarbamates with Indoles: C-S Bond Formation
Halimehjani, Azim Ziyaei
Shokrgozar, Sahar
Beier, Petr
JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (10): : 5778 - 5783
[45] Sulfenylation of C-H Bonds for C-S Bond Formation under Metal-Free Conditions
Dong, Dao-Qing
Hao, Shuang-Hong
Yang, Dao-Shan
Li, Li-Xia
Wang, Zu-Li
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (45) : 6576 - 6592
[46] One-pot synthesis of pyrimidines under solvent-free conditions
Ghorbani-Vaghei, Ramin
Karimi-Nami, Rahman
Toghraei-Semiromi, Zahra
Amiri, Mostafa
Salimi, Zahra
Ghavidel, Mehdi
COMPTES RENDUS CHIMIE, 2014, 17 (04) : 324 - 330
[47] Electrochemical Synthesis of Thienoacene Derivatives: Transition-Metal-Free Dehydrogenative C-S Coupling Promoted by a Halogen Mediator
Mitsudo, Koichi
Matsuo, Ren
Yonezawa, Toki
Inoue, Haruka
Mandai, Hiroki
Suga, Seiji
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (20) : 7803 - 7807
[48] Transition metal-free addition of dithiocarbamates to alkynes: one-pot regioselective synthesis of S-vinyl dithiocarbamates under solvent-free conditions
Fezzeh Aryanasab
Mohammad Reza Saidi
Monatshefte für Chemie - Chemical Monthly, 2014, 145 : 521 - 526
[49] Transition metal-free addition of dithiocarbamates to alkynes: one-pot regioselective synthesis of S-vinyl dithiocarbamates under solvent-free conditions
Aryanasab, Fezzeh
Saidi, Mohammad Reza
MONATSHEFTE FUR CHEMIE, 2014, 145 (03): : 521 - 526
[50] One-pot cyclization/decarboxylation of α-keto acids and acylhydrazines for the synthesis of 2,5-disubstituted 1,3,4-oxadiazoles under transition-metal-free conditions
Gao, Peng
Wang, Juan
Bai, Zijing
Cheng, Hualei
Xiao, Jian
Lai, Mengnan
Yang, Desuo
Fan, Mingjin
TETRAHEDRON LETTERS, 2016, 57 (41) : 4616 - 4619

← 1 2 3 4 5 →