Sulfenylation of C-H Bonds for C-S Bond Formation under Metal-Free Conditions

被引：101
|
作者：
Dong, Dao-Qing [1 ]
Hao, Shuang-Hong [1 ]
Yang, Dao-Shan [2 ,3 ]
Li, Li-Xia [1 ]
Wang, Zu-Li [1 ]
机构：
[1] Qingdao Agr Univ, Coll Chem & Pharmaceut Sci, Qingdao 266109, Peoples R China
[2] Qufu Normal Univ, Sch Chem & Chem Engn, Key Lab Life Organ Anal, Qufu 273165, Shandong, Peoples R China
[3] Qufu Normal Univ, Sch Chem & Chem Engn, Key Lab Pharmaceut Intermediates & Anal Nat Med, Qufu 273165, Shandong, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 45期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Sulfenylation; C-S bonds; Metal-free; Disulfides; Succinimides; Reaction mechanisms; Aromatic substitution; Synthetic methods; CATALYZED REGIOSELECTIVE SULFENYLATION; ARYL SULFONYL HYDRAZIDES; BASE-BRONSTED ACID; ENANTIOSELECTIVE SULFENYLATION; ALPHA-SULFENYLATION; COUPLING REACTION; INDOLES; IMIDAZOHETEROCYCLES; DERIVATIVES; SYSTEM;
D O I：
10.1002/ejoc.201700853
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sulfenylation of C-H bonds for C-S bond formation under metal-free conditions has become established as a powerful tool in organic chemistry. Various sulfenylation reagents such as thiols, disulfides, sulfinic acids, and so on have been employed for sulfenynlation reactions. In this review we mainly summarize the recent advances (2014 to the present) in this area and also discuss the mechanisms.
引用
收藏
页码：6576 / 6592
页数：17
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