Recent advances in sulfenylation of C(sp3)-H bond under transition metal-free conditions

被引：0

作者：

Xin-Ming Xu ^{[1
]}

De-Mao Chen ^{[2
,3
]}

Zu-Li Wang ^{[2
]}

机构：

[1] College of Chemistry and Chemical Engineering, Yantai University

[2] College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University

[3] School of Chemistry and Chemical Engineering, Hunan University of Science and Technology

来源：

Chinese Chemical Letters | 2020年 / 31卷 / 01期

关键词：

Sulfenylation; C(sp~3)-H bond; Metal-free; Reaction mechanism; Synthetic method;

D O I：

暂无

中图分类号：

O621.25 [];

学科分类号：

070303 ; 081704 ;

摘要：

In recent years,the transition metal-free sulfenylation of C-H bond for C-S formation has been rapidly advanced and has become an eco-friendly synthetic tool for pharmacists and organic chemists.Various natural or bioactive molecules such as(hetero)arenes,olefins,carbonyl compounds,alkanes,have been employed for sulfenylating reactions.This review will focus on the recent five-year advances in C-S bond formation via direct sulfenylation of C(sp3)—H bonds under metal-free conditions and elaborate their mechanisms from a new perspective.

引用

页码：49 / 57

页数：9

共 50 条

[1] Recent advances in sulfenylation of C(sp3)-H bond under transition metal-free conditions
Xu, Xin-Ming
Chen, De-Mao
Wang, Zu-Li
[J]. CHINESE CHEMICAL LETTERS, 2020, 31 (01) : 49 - 57
[2] Recent Advances in Transition Metal-Free Sulfenylation of Indoles
Xu, Xinming
Li, Jiazhu
Wang, Zuli
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2020, 40 (04) : 886 - 898
[3] Transition metal-free C(sp3)-H selenation of β-ketosulfones
Abdukerem, Dilshat
Chen, Hui
Mao, Zechuan
Xia, Kun
Zhu, Wenli
Liu, Changhong
Yu, Yuming
Abdukader, Ablimit
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (10) : 2075 - 2080
[4] Direct intramolecular C(sp3)-H bond sulfonamidation to synthesize benzosultam derivatives under metal-free conditions
Zhang, He
Sun, Meng-Chan
Yin, Li-Ming
Wei, Donghui
Song, Mao-Ping
Yang, Dandan
Niu, Jun-Long
[J]. ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (24) : 6888 - 6894
[5] Recent Development of Metal-Free Direct Asymmetric Functionalization of Benzylic C(sp3)-H Bond
Jiang, Xin
Wang, Sidun
Guo, Guimin
Lu, Beili
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (04) : 841 - 857
[6] Transition metal-free C(sp3)-H bond coupling among three methyl groups
Liu, Yufeng
Zhan, Xi
Ji, Pengyi
Xu, Jingwen
Liu, Qiang
Luo, Weiping
Chen, Tieqiao
Guo, Cancheng
[J]. CHEMICAL COMMUNICATIONS, 2017, 53 (38) : 5346 - 5349
[7] Transition Metal-Free, Free-Radical Sulfenylation of the α-C(sp3)-H Bond in Arylacetamides and Its Application Toward 2-Thiomethyl Benzoxazoles Synthesis
Tian, Shanghui
Wang, Chaoli
Xia, Jianhui
Wan, Jie-Ping
Liu, Yunyun
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (19) : 4627 - 4631
[8] Efficient C-S Bond Formation by Direct Functionalization of C(sp3)-H Bond Adjacent to Heteroatoms under Metal-Free Conditions
Zhao, Feng
Tan, Qi
Wang, Dahan
Chen, Jinjin
Deng, Guo-Jun
[J]. ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (17) : 4075 - 4081
[9] Sulfenylation of C-H Bonds for C-S Bond Formation under Metal-Free Conditions
Dong, Dao-Qing
Hao, Shuang-Hong
Yang, Dao-Shan
Li, Li-Xia
Wang, Zu-Li
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 2017 (45) : 6576 - 6592
[10] Recent Advances in Radical Initiated C-N Bond Formation under Transition Metal-Free Conditions
Yuan, Sitian
Wang, Yanhua
Qiu, Guanyinsheng
Liu, Jinbiao
[J]. CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (03) : 566 - 576

← 1 2 3 4 5 →