One-Pot Synthesis of Thiocarbamide Esters: Construction of C-S Bonds under Transition-Metal-Free Conditions

被引：0
|
作者：
Deng, Shi-Hao [1 ]
Yu, Jun-Xia [1 ]
Xiao, Hua-Qing [5 ]
Dong, Zhi-Bing [1 ,2 ,3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China
[2] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
[4] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China
[5] Hubei Greenhome Mat Technol, Xiantao 433000, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 46期
关键词：
C-S bond; One-Pot; Synthesis; Transition-Metal free; Thiocarbamide Esters; ARYLBORONIC ACIDS; THIOETHERS; CHLORIDES; DIARYL; THIOLS;
D O I：
10.1002/ejoc.202201167
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient and effective method for the construction of C-S bond under transition-metal free conditions was reported. Thus, diverse thiocarbamide esters could be smoothly obtained in moderate to good yields from inexpensive and readily available starting materials, such as phenyl isothiocyanate, alcohols and benzyl halides. This method features mild conditions, easy operation, short reaction time and broad substrate scopes, providing a facile and convenient strategy for the preparation of some compounds with potential biological activities.
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页数：4
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