Kinetics and mechanism of gallium discharge and ionization in an alkaline solution of potassium fluoride

被引：5
|
作者：
Kozin, L. F. [1 ]
Gaidin, A. V. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Vernadskii Inst Gen & Inorgan Chem, Kiev, Ukraine
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2009年 / 82卷 / 03期
关键词：
DIFFERENTIAL CAPACITANCE;
D O I：
10.1134/S1070427209030124
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mechanism of gallium discharge and ionization on a liquid gallium electrode in a fluoride-alkaline electrolyte was studied. The exchange currents, transfer coefficients in the cathodic and anodic processes, and the activation energy of the electrode process were determined. The conditions in which gallium(I) ion-intermediates are formed were analyzed. The coordination numbers of the gallium complexes formed in alkaline fluoride solutions were calculated.
引用
收藏
页码：406 / 415
页数：10
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