Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)

被引：0
|
作者：
Iqab, A. [1 ]
机构：
[1] Arab Amer Univ, Dept Chem, Jenin, Palestine
来源：
EGYPTIAN JOURNAL OF CHEMISTRY | 2021年 / 64卷 / 03期
关键词：
2-methylindole; hexacyanoferrate(III); 2-methylindolin-3-one; kinetics and oxidation; INDOLE;
D O I：
10.21608/EJCHEM.2020.22459.2338
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 2-methylindole with hexacyanoferrate(III) in alkaline media to produce the corresponding 2-methylindolin-3one has been studied at constant temperature and ionic strength. The reaction followed first order kinetics with respect to [2methylindole], [OH-] and [Fe(CN)63-]. The effects of added electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. On the basis of experimental observations, a probable reaction mechanism has been proposed.
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页码：1441 / 1446
页数：6
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