Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)

被引：0

作者：

Iqab, A. ^{[1
]}

机构：

[1] Arab Amer Univ, Dept Chem, Jenin, Palestine

来源：

EGYPTIAN JOURNAL OF CHEMISTRY | 2021年 / 64卷 / 03期

关键词：

2-methylindole; hexacyanoferrate(III); 2-methylindolin-3-one; kinetics and oxidation; INDOLE;

D O I：

10.21608/EJCHEM.2020.22459.2338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-methylindole with hexacyanoferrate(III) in alkaline media to produce the corresponding 2-methylindolin-3one has been studied at constant temperature and ionic strength. The reaction followed first order kinetics with respect to [2methylindole], [OH-] and [Fe(CN)63-]. The effects of added electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. On the basis of experimental observations, a probable reaction mechanism has been proposed.

引用

页码：1441 / 1446

页数：6

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