Kinetics and mechanism of gallium discharge and ionization in an alkaline solution of potassium fluoride

被引：5
|
作者：
Kozin, L. F. [1 ]
Gaidin, A. V. [1 ]
机构：
[1] Natl Acad Sci Ukraine, Vernadskii Inst Gen & Inorgan Chem, Kiev, Ukraine
来源：
RUSSIAN JOURNAL OF APPLIED CHEMISTRY | 2009年 / 82卷 / 03期
关键词：
DIFFERENTIAL CAPACITANCE;
D O I：
10.1134/S1070427209030124
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mechanism of gallium discharge and ionization on a liquid gallium electrode in a fluoride-alkaline electrolyte was studied. The exchange currents, transfer coefficients in the cathodic and anodic processes, and the activation energy of the electrode process were determined. The conditions in which gallium(I) ion-intermediates are formed were analyzed. The coordination numbers of the gallium complexes formed in alkaline fluoride solutions were calculated.
引用
收藏
页码：406 / 415
页数：10
相关论文
共 50 条
  • [41] THE MECHANISM OF IONIZATION IN SOLUTION
    SADEK, H
    SCIENCE, 1950, 111 (2883) : 338 - 339
  • [42] Kinetics and Mechanism of Lithium Extraction from α-Spodumene in Potassium Hydroxide Solution
    Qiu, Shengbo
    Zhu, Yue
    Jiang, Youfa
    Liu, Chenglin
    Yu, Jianguo
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2022, 61 (41) : 15103 - 15113
  • [43] OXIDATION OF ETHANEDIOL AND PROPANEDIOL BY POTASSIUM FERRATE(VI) IN ALKALINE MEDIA - KINETICS AND MECHANISM STUDY
    Liu, Hongru
    Shan, Jinhuan
    Zhang, Hong
    Wang, Dan
    OXIDATION COMMUNICATIONS, 2016, 39 (04): : 2856 - 2863
  • [44] IONIZATION MECHANISM OF GALLIUM ON A TUNGSTEN FIELD EMITTER
    CULBERTSON, RJ
    ROBERTSON, GH
    SAKURAI, T
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1979, 16 (06): : 1868 - 1870
  • [45] KINETICS AND MECHANISM OF GROWTH OF GALLIUM CRYSTALS
    BORISOV, VT
    GOLIKOV, IN
    MATVEEV, YE
    SOVIET PHYSICS CRYSTALLOGRAPHY, USSR, 1969, 13 (05): : 756 - &
  • [46] Oxidation of ethanethiol in aqueous alkaline solution by ferrate(VI): Kinetics, stoichiometry and mechanism
    Wang, Jing
    Zheng, Tong
    Cai, Chen
    Zhang, Yanxiang
    Liu, Huiling
    CHEMICAL ENGINEERING JOURNAL, 2019, 361 : 1557 - 1564
  • [47] Kinetics and mechanism of sulphite oxidation on a rotating platinum disc electrode in an alkaline solution
    Skavas, Erling
    Hemmingsen, Tor
    ELECTROCHIMICA ACTA, 2007, 52 (11) : 3510 - 3517
  • [48] KINETICS AND MECHANISM OF OXIDATION OF HYPOPHOSPHITE BY HEXACYANOFERRATE(III) ION IN ALKALINE-SOLUTION
    MOHAN, D
    CHHABRA, VK
    GUPTA, YK
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (18): : 1737 - 1740
  • [49] Kinetics, thermodynamic and mechanism of the oxidation of vanillin with octacyanotungstate(V) ions in alkaline solution
    Aizenstadt, A
    Popova, N
    Bogolitsyn, K
    ADVANCES IN LIGNOCELLULOSICS CHEMISTRY FOR ECOLOGICALLY FRIENDLY PULPING AND BLEACHING TECHNOLOGIES, 1998, : 203 - 204
  • [50] On the kinetics and mechanism of the oxidation of I- by •OH/O•- in alkaline aqueous solution
    Mulazzani, QG
    Buxton, GV
    CHEMICAL PHYSICS LETTERS, 2006, 421 (1-3) : 261 - 265
12345