Practical and environmentally friendly epoxidation of olefins using oxone

被引:63
|
作者
Hashimoto, N [1 ]
Kanda, A [1 ]
机构
[1] Fujisawa Pharmaceut Co Ltd, Chem Dev Labs, Yodogawa Ku, Osaka 5328514, Japan
关键词
D O I
10.1021/op025511f
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A practical and efficient epoxidation of aromatic olefins using Oxone in a two-phase system (ethyl acetate-water) is described. The reported method is suitable for large-scale synthesis and does not require phase transfer catalyst (PTC) or pH control.
引用
收藏
页码:405 / 406
页数:2
相关论文
共 50 条
  • [1] Fluorinated chiral secondary amines as catalysts for epoxidation of olefins with oxone
    Ho, CY
    Chen, YC
    Wong, MK
    Yang, D
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (03): : 898 - 906
  • [2] Chiral ketone-catalyzed asymmetric epoxidation of olefins with Oxone®
    Matsumoto, K
    Tomioka, K
    TETRAHEDRON LETTERS, 2002, 43 (04) : 631 - 633
  • [3] Environmentally friendly epoxidation of olefins under phase-transfer catalysis conditions with hydrogen peroxide
    Mahha, Yahdih
    Salles, Laurent
    Piquemal, Jean-Yves
    Briot, Emmanuel
    Atlamsani, Ahmed
    Bregeault, Jean-Marie
    JOURNAL OF CATALYSIS, 2007, 249 (02) : 338 - 348
  • [4] Design of a highly efficient catalyst for the oxaziridinium-mediated epoxidation of olefins by Oxone®
    Bohé, L
    Kammoun, M
    TETRAHEDRON LETTERS, 2004, 45 (04) : 747 - 751
  • [5] Oxidation of Long-Chain α-Olefins Using Environmentally-Friendly Oxidants
    Peckh, Kamil
    Lisicki, Dawid
    Talik, Gabriela
    Orlinska, Beata
    MATERIALS, 2020, 13 (20) : 1 - 14
  • [6] Modified and environmentally friendly oxidation of phosphorane ylides to vicinal tricarbonyls using unsupported moist Oxone in dichloromethane
    Lee, Kieseung
    Lee, Richard S.
    Lee, Joanne S.
    SYNTHETIC COMMUNICATIONS, 2020, 50 (08) : 1141 - 1146
  • [7] ALKOXYBROMINATION OF OLEFINS USING AMMONIUM BROMIDE AND OXONE
    Kumar, Macharla Arun
    Naresh, Mameda
    Rohitha, Chozhiyath Nappunni
    Narender, Nama
    SYNTHETIC COMMUNICATIONS, 2013, 43 (23) : 3121 - 3129
  • [8] Nano-layered manganese oxides as low-cost, easily synthesized, environmentally friendly and efficient catalysts for epoxidation of olefins
    Amini, Mojtaba
    Najafpour, Mohammad Mahdi
    Nayeri, Sara
    Pashaei, Babak
    Bagherzadeh, Mojtaba
    RSC ADVANCES, 2012, 2 (09) : 3654 - 3657
  • [9] Environmentally friendly catalysis using supported reagents: Catalytic epoxidation using a chemically modified silica gel
    Butterworth, AJ
    Clark, JH
    Walton, PH
    Barlow, SJ
    CHEMICAL COMMUNICATIONS, 1996, (16) : 1859 - 1860
  • [10] CATALYTIC EPOXIDATION OF ALKENES WITH OXONE
    DENMARK, SE
    FORBES, DC
    HAYS, DS
    DEPUE, JS
    WILDE, RG
    JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05): : 1391 - 1407