Practical and environmentally friendly epoxidation of olefins using oxone

被引：63
|
作者：
Hashimoto, N [1 ]
Kanda, A [1 ]
机构：
[1] Fujisawa Pharmaceut Co Ltd, Chem Dev Labs, Yodogawa Ku, Osaka 5328514, Japan
来源：
ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2002年 / 6卷 / 04期
关键词：
D O I：
10.1021/op025511f
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A practical and efficient epoxidation of aromatic olefins using Oxone in a two-phase system (ethyl acetate-water) is described. The reported method is suitable for large-scale synthesis and does not require phase transfer catalyst (PTC) or pH control.
引用
收藏
页码：405 / 406
页数：2
相关论文
共 50 条
  • [31] CATALYSIS OF THE EPOXIDATION OF OLEFINS
    LASZLO, P
    BOUHLEL, E
    LEVART, M
    SINGH, GP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 49 - PETR
  • [32] EPOXIDATION OF OLEFINS BY OXAZIRIDINES
    DAVIS, FA
    ABDULMALIK, NF
    AWAD, SB
    HARAKAL, ME
    TETRAHEDRON LETTERS, 1981, 22 (10) : 917 - 920
  • [33] The direct epoxidation of higher olefins using molecular oxygen
    Monnier, JR
    APPLIED CATALYSIS A-GENERAL, 2001, 221 (1-2) : 73 - 91
  • [34] SELECTIVE EPOXIDATION OF OLEFINS USING HYDROGEN-PEROXIDE
    HAUTHAL, HG
    FRANZ, K
    HINDEMITH, H
    ZEITSCHRIFT FUR CHEMIE, 1978, 18 (03): : 113 - 113
  • [35] Epoxidation of olefins using chiral salen vanadium catalysts
    Miranda, James A.
    Martin, Eric J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
  • [36] Enantioselective epoxidation of electrophilic olefins by using glycosyl hydroperoxides
    Kosnik, Woietta
    Bocian, Wojciech
    Kozerski, Lech
    Tvaroska, Igor
    Chmielewski, Marek
    CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (20) : 6087 - 6097
  • [37] A simple and efficient protocol for epoxidation of olefins using dimethyldioxirane
    Ferraz, HMC
    Muzzi, RM
    Vieira, TD
    Viertler, H
    TETRAHEDRON LETTERS, 2000, 41 (26) : 5021 - 5023
  • [38] An environmentally friendly and practical method for obtaining color on stainless steel by interference
    Vasconcelos, KDO
    Bocchi, N
    Rocha, RC
    Biaggio, SR
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) : B491 - B494
  • [39] Regio- and stereoselective hydroxybromination and dibromination of olefins using ammonium bromide and oxone®
    Macharla, Arun Kumar
    Nappunni, Rohitha Chozhiyath
    Nama, Narender
    TETRAHEDRON LETTERS, 2012, 53 (11) : 1401 - 1405
  • [40] Flavin-catalyzed generation of diimide: An environmentally friendly method for the aerobic hydrogenation of olefins
    Imada, Yasushi
    Iida, Hiroki
    Naota, Takeshi
    Journal of the American Chemical Society, 2005, 127 (42): : 14544 - 14545
12345