Practical and environmentally friendly epoxidation of olefins using oxone

被引：63
|
作者：
Hashimoto, N [1 ]
Kanda, A [1 ]
机构：
[1] Fujisawa Pharmaceut Co Ltd, Chem Dev Labs, Yodogawa Ku, Osaka 5328514, Japan
来源：
ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2002年 / 6卷 / 04期
关键词：
D O I：
10.1021/op025511f
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A practical and efficient epoxidation of aromatic olefins using Oxone in a two-phase system (ethyl acetate-water) is described. The reported method is suitable for large-scale synthesis and does not require phase transfer catalyst (PTC) or pH control.
引用
收藏
页码：405 / 406
页数：2
相关论文
共 50 条
  • [21] Epoxidation of cyclopentene by a low cost and environmentally friendly bicarbonate/peroxide/manganese system
    Hincapie, Beatriz
    Llano, Sandra M.
    Garces, Hector F.
    Espinal, Diego
    Suib, Steven L.
    Garces, Luis J.
    ADSORPTION SCIENCE & TECHNOLOGY, 2018, 36 (1-2) : 9 - 22
  • [22] A practical, cheap and environmentally friendly preparation of bismuth(III) trifluoromethanesulfonate
    Répichet, S
    Zwick, A
    Vendier, L
    Le Roux, C
    Dubac, J
    TETRAHEDRON LETTERS, 2002, 43 (06) : 993 - 995
  • [23] A practical and environmentally friendly protocol for synthesis of α-deuterated carboxylic acids
    Wennerberg, Johan
    Dreisch, Klaus
    JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 2023, 66 (4-6): : 138 - 144
  • [24] A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly route
    Sheremetev, Aleksei B.
    Lyalin, Boris V.
    Kozeev, Andrei M.
    Palysaeva, Nadezhda V.
    Struchkova, Marina I.
    Suponitsky, Kyrill Yu.
    RSC ADVANCES, 2015, 5 (47): : 37617 - 37625
  • [25] Base-catalyzed amination of olefins: an example of an environmentally friendly synthesis of amines
    Beller, M
    Breindl, C
    CHEMOSPHERE, 2001, 43 (01) : 21 - 26
  • [26] Vicinal Dichlorination of Olefins Using NH4Cl and Oxone®
    Swamy, Peraka
    Reddy, Marri Mahender
    Kumar, Macharla Arun
    Naresh, Mameda
    Narender, Nama
    SYNTHESIS-STUTTGART, 2014, 46 (02): : 251 - 257
  • [27] α-functionalised ketones as promoters of alkene epoxidation by Oxone®
    Armstrong, A
    Hayter, BR
    TETRAHEDRON, 1999, 55 (36) : 11119 - 11126
  • [28] ELECTROCHEMICAL EPOXIDATION OF OLEFINS
    van der Eijk, J. M.
    Peters, Th. J.
    de Wit, N.
    Colijn, H. A.
    CATALYSIS TODAY, 1988, 3 (2-3) : 259 - 266
  • [29] CATALYSIS OF THE EPOXIDATION OF OLEFINS
    LASZLO, P
    LEVART, M
    SINGH, GP
    TETRAHEDRON LETTERS, 1991, 32 (27) : 3167 - 3168
  • [30] Epoxidation of Olefins with dioxiranes
    Gao, YJ
    Ma, JJ
    Wang, C
    Zhang, YQ
    Cui, PL
    Zang, XH
    Zhou, YX
    Tang, RX
    Li, YM
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (07) : 745 - 750
12345