Modified and environmentally friendly oxidation of phosphorane ylides to vicinal tricarbonyls using unsupported moist Oxone in dichloromethane

被引：4

作者：

Lee, Kieseung ^{[1
,2
]}

Lee, Richard S. ^{[3
]}

Lee, Joanne S. ^{[4
]}

机构：

[1] Woosuk Univ, Dept Appl Chem, Chonbuk, South Korea

[2] Woosuk Univ, Dept Pharmaceut Engn, Chonbuk, South Korea

[3] Univ Southern Calif, Sch Pharm, Los Angeles, CA 90007 USA

[4] Univ Pacific, Sch Pharm, Stockton, CA 95211 USA

来源：

SYNTHETIC COMMUNICATIONS | 2020年 / 50卷 / 08期

关键词：

Surface-mediated reaction; unsupported moist Oxone; phosphorane ylide; vicinal tricarbonyl; SURFACE-MEDIATED REACTIONS; SELECTIVE OXIDATION; CHEMISTRY; METHODOLOGY; INHIBITORS;

D O I：

10.1080/00397911.2020.1719422

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Modified and eco-friendly oxidation of phosphorane ylides to the corresponding vicinal tricarbonyls (VTC) using unsupported moist Oxone in dichloromethane at room temperature is described. This green oxidation protocol is simple, mild, and highly efficient to operate, and allowing a chemoselective preparation of VTC from various phosphorane ylides without tedious workup procedures of extraction/drying process in excellent yields.

引用

页码：1141 / 1146

页数：6

共 2 条

[1] A practical procedure for the selective oxidation of phosphorus keto ylides to vicinal tricarbonyls using moist magnesium monoperoxyphthalate (MMPP) in dichloromethane at ambient temperature
Lee, K
Im, JM
TETRAHEDRON LETTERS, 2001, 42 (08) : 1539 - 1542
[2] Enhanced degradation and removal of ciprofloxacin and ofloxacin through advanced oxidation and adsorption processes using environmentally friendly modified carbon nanotubes
Oliveira M.G.
Rocca D.G.D.
Moreira R.D.F.P.M.
da Silva M.G.C.
Vieira M.G.A.
Environmental Science and Pollution Research, 2024, 31 (20) : 29957 - 29970

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