An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

被引：7
|
作者：
Zhang, Qian [1 ,2 ]
Li, Juanjuan [1 ,2 ]
Li, Jiale [2 ]
Yuan, Songdong [1 ,2 ]
Li, Dong [1 ]
机构：
[1] Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Peoples R China
[2] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 41期
基金：
中国国家自然科学基金;
关键词：
Cobalt; Aroylation; Amine; Aroyl peroxide; ASYMMETRIC ALPHA-BENZOYLOXYLATION; DECARBOXYLATIVE ORTHO-ARYLATION; H BOND FUNCTIONALIZATION; ACYL PEROXIDES; COUPLING REAGENTS; SECONDARY AMIDES; BENZOYL PEROXIDE; CARBOXYLIC-ACIDS; TRANSAMIDATION; REACTIVITY;
D O I：
10.1016/j.tetlet.2020.152399
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and facile cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides was developed for the synthesis of aryl amides. It was unprecedented that C-N bond formation product was selectively generated without the common N-O bond formation product. Aroyl peroxides act as the sole aroylation reagent without additional base or oxidant. The reactions proceeded under mild conditions and showed broad substrates scope with a series of primary amines and aroyl peroxides. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：5
相关论文
共 50 条
  • [41] Cobalt-Catalyzed (Hetero)arylation of Saturated Cyclic Amines with Grignard Reagents
    Barre, Baptiste
    Gonnard, Laurine
    Guerinot, Amandine
    Cossy, Janine
    MOLECULES, 2018, 23 (06):
  • [42] Cobalt-catalyzed synthesis of amides from alkenes and amines promoted by light
    Faculak, Mason S.
    Veatch, Alexander M.
    Alexanian, Erik J.
    SCIENCE, 2024, 383 (6678) : 77 - 81
  • [43] Cobalt-catalyzed (Z)-selective semihydrogenation of alkynes with molecular hydrogen
    Chen, Caiyou
    Huang, Yi
    Zhang, Zongpeng
    Dong, Xiu-Qin
    Zhang, Xumu
    CHEMICAL COMMUNICATIONS, 2017, 53 (33) : 4612 - 4615
  • [44] Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines
    Yamamoto, Shohei
    Saga, Yutaka
    Andou, Takashi
    Matsunaga, Shigeki
    Kanai, Motomu
    ADVANCED SYNTHESIS & CATALYSIS, 2014, 356 (2-3) : 401 - 405
  • [45] Reusable Cobalt-Catalyzed Selective Transfer Hydrogenation of Azoarenes and Nitroarenes
    Dey, Sadhan
    Panja, Dibyajyoti
    Sau, Anirban
    Thakur, Seema D. D.
    Kundu, Sabuj
    JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (14): : 10048 - 10057
  • [46] Mild and Selective Cobalt-Catalyzed Chemodivergent Transfer Hydrogenation of Nitriles
    Shao, Zhihui
    Fu, Shaomin
    Wei, Mufeng
    Zhou, Shaolin
    Liu, Qiang
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (47) : 14653 - 14657
  • [47] Cobalt-Catalyzed Selective Unsymmetrical Dioxidation of gem-Difluoroalkenes
    Orsi, Douglas L.
    Douglas, Justin T.
    Sorrentino, Jacob P.
    Altman, Ryan A.
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (16): : 10451 - 10465
  • [48] Cobalt-Catalyzed Z-Selective Hydrosilylation of Terminal Alkynes
    Teo, Wei Jie
    Wang, Chao
    Tan, Ye Wei
    Ge, Shaozhong
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (15) : 4328 - 4332
  • [49] Cobalt-catalyzed selective dehydrocoupling polymerization of prochiral silanes and diols
    Zhai, Xiao-Yong
    Wang, Xiao-Qing
    Zhou, Yong-Gui
    EUROPEAN POLYMER JOURNAL, 2020, 134
  • [50] Cobalt-Catalyzed Efficient Asymmetric Hydrogenation of α-Primary Amino Ketones
    Yang, Huiwen
    Hu, Yanhua
    Zou, Yashi
    Zhang, Zhenfeng
    Zhang, Wanbin
    JACS AU, 2023, 3 (11): : 2981 - 2986
12345