An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

被引：7
|
作者：
Zhang, Qian [1 ,2 ]
Li, Juanjuan [1 ,2 ]
Li, Jiale [2 ]
Yuan, Songdong [1 ,2 ]
Li, Dong [1 ]
机构：
[1] Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Peoples R China
[2] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 41期
基金：
中国国家自然科学基金;
关键词：
Cobalt; Aroylation; Amine; Aroyl peroxide; ASYMMETRIC ALPHA-BENZOYLOXYLATION; DECARBOXYLATIVE ORTHO-ARYLATION; H BOND FUNCTIONALIZATION; ACYL PEROXIDES; COUPLING REAGENTS; SECONDARY AMIDES; BENZOYL PEROXIDE; CARBOXYLIC-ACIDS; TRANSAMIDATION; REACTIVITY;
D O I：
10.1016/j.tetlet.2020.152399
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and facile cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides was developed for the synthesis of aryl amides. It was unprecedented that C-N bond formation product was selectively generated without the common N-O bond formation product. Aroyl peroxides act as the sole aroylation reagent without additional base or oxidant. The reactions proceeded under mild conditions and showed broad substrates scope with a series of primary amines and aroyl peroxides. (C) 2020 Elsevier Ltd. All rights reserved.
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页数：5
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