An unprecedented cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides

被引：7
|
作者：
Zhang, Qian [1 ,2 ]
Li, Juanjuan [1 ,2 ]
Li, Jiale [2 ]
Yuan, Songdong [1 ,2 ]
Li, Dong [1 ]
机构：
[1] Hubei Univ Technol, Hubei Collaborat Innovat Ctr High Efficiency Util, Wuhan 430068, Peoples R China
[2] Hubei Univ Technol, Sch Mat & Chem Engn, Wuhan 430068, Peoples R China
来源：
TETRAHEDRON LETTERS | 2020年 / 61卷 / 41期
基金：
中国国家自然科学基金;
关键词：
Cobalt; Aroylation; Amine; Aroyl peroxide; ASYMMETRIC ALPHA-BENZOYLOXYLATION; DECARBOXYLATIVE ORTHO-ARYLATION; H BOND FUNCTIONALIZATION; ACYL PEROXIDES; COUPLING REAGENTS; SECONDARY AMIDES; BENZOYL PEROXIDE; CARBOXYLIC-ACIDS; TRANSAMIDATION; REACTIVITY;
D O I：
10.1016/j.tetlet.2020.152399
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and facile cobalt-catalyzed selective aroylation of primary amines with aroyl peroxides was developed for the synthesis of aryl amides. It was unprecedented that C-N bond formation product was selectively generated without the common N-O bond formation product. Aroyl peroxides act as the sole aroylation reagent without additional base or oxidant. The reactions proceeded under mild conditions and showed broad substrates scope with a series of primary amines and aroyl peroxides. (C) 2020 Elsevier Ltd. All rights reserved.
引用
收藏
页数：5
相关论文
共 50 条
  • [31] Cobalt-catalyzed branched selective hydroallylation of terminal alkynes
    Jieping Chen
    Jiale Ying
    Zhan Lu
    Nature Communications, 13
  • [32] Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines
    Li, Huaifeng
    Al-Dakhil, Abdullah
    Lupp, Daniel
    Gholap, Sandeep Suryabhan
    Lai, Zhiping
    Liang, Lan-Chang
    Huang, Kuo-Wei
    ORGANIC LETTERS, 2018, 20 (20) : 6430 - 6435
  • [33] Cobalt-catalyzed selective conversion of diallylanilines and arylimines to quinolines
    Jacob, J
    Cavalier, CM
    Jones, WD
    Godleski, SA
    Valente, RR
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) : 565 - 570
  • [34] Cobalt-catalyzed highly selective hydroxylation of organohydrosilanes and hydrosiloxanes
    Guo, Peng
    Cheng, Ling-Chao
    He, Xinglei
    Ye, Ke-Yin
    ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (21): : 5802 - 5807
  • [35] Cobalt-Catalyzed Facial-Selective Hydroalkylation of Cyclopropenes
    Zhang, Zhi-Lin
    Li, Zhen
    Xu, Yuan-Tai
    Yu, Lu
    Kuang, Jian
    Li, Yan
    Wang, Jia-Wang
    Tian, Changlin
    Lu, Xi
    Fu, Yao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2023, 62 (30)
  • [36] Cobalt-Catalyzed (E)-β-Selective Hydrogermylation of Terminal Alkynes
    Radzhabov, Maxim R.
    Mankad, Neal P.
    ORGANIC LETTERS, 2021, 23 (08) : 3221 - 3226
  • [37] Cobalt-Catalyzed C-H Allylation of Arenes with Allylic Amines
    Yan, Rui
    Yu, Hang
    Wang, Zhong-Xia
    CHINESE JOURNAL OF CHEMISTRY, 2021, 39 (05) : 1205 - 1210
  • [38] Cobalt-catalyzed Synthesis of Homoallylic Amines from Imines and Terminal Alkenes
    Tanaka, Ryo
    Kojima, Masahiro
    Yoshino, Tatsuhiko
    Matsunaga, Shigeki
    CHEMISTRY LETTERS, 2019, 48 (09) : 1046 - 1049
  • [39] Efficient Cobalt-Catalyzed Coupling of Amines and Siloxanes to Prepare Ceramics and Polymers
    Sharma, Anuja
    Bean, Ren H. H.
    Long, Timothy E. E.
    Trovitch, Ryan J. J.
    ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2023, 11 (30) : 11172 - 11180
  • [40] Cobalt-Catalyzed Umpolung Alkylation of Imines To Generate α-Branched Aliphatic Amines
    Wan, Li-Qiang
    Cao, Jin-Ge
    Niu, Dawen
    Zhang, Xia
    ORGANIC LETTERS, 2021, 23 (10) : 3818 - 3822
12345