Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules

被引：456
|
作者：
Chen, Banglin [1 ]
Ma, Shengqian
Zapata, Fatima
Fronczek, Frank R.
Lobkovsky, Emil B.
Zhou, Hong-Cai
机构：
[1] Univ Texas, Dept Chem, Edinburg, TX 78541 USA
[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[4] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 04期
关键词：
D O I：
10.1021/ic0616434
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)(0.5) (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 A, which are interconnected by pore windows of 2.0 x 3.2 A, 3a shows highly selective sorption behaviors of gas molecules.
引用
收藏
页码：1233 / 1236
页数：4
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