Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

被引：91

作者：

Chen, Banglin ^{[1
]}

Ji, Yanyan ^{[2
]}

Xue, Ming ^{[1
,2
]}

Fronczek, Frank R. ^{[3
]}

Hurtado, Eric J. ^{[1
]}

Mondal, Jalal U. ^{[1
]}

Liang, Chengdu ^{[4
,5
]}

Dai, Sheng ^{[4
,5
]}

机构：

[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

[5] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 13期

关键词：

D O I：

10.1021/ic8004008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4'-Bipy)(0.5)center dot 0.55H(2)O (R-GLA-Me = R-2-methylglutarate, 4,4'-Bipy = 4,4'-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 angstrom, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.

引用

页码：5543 / 5545

页数：3

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