Metal-organic framework with rationally tuned micropores for selective adsorption of water over methanol

被引：91
|
作者：
Chen, Banglin [1 ]
Ji, Yanyan [2 ]
Xue, Ming [1 ,2 ]
Fronczek, Frank R. [3 ]
Hurtado, Eric J. [1 ]
Mondal, Jalal U. [1 ]
Liang, Chengdu [4 ,5 ]
Dai, Sheng [4 ,5 ]
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78539 USA
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA
[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA
[5] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
来源：
INORGANIC CHEMISTRY | 2008年 / 47卷 / 13期
关键词：
D O I：
10.1021/ic8004008
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A microporous metal-organic framework 1, Cu(R-GLA-Me)(4,4'-Bipy)(0.5)center dot 0.55H(2)O (R-GLA-Me = R-2-methylglutarate, 4,4'-Bipy = 4,4'-bipyridine), with a primitive cubic net was synthesized and characterized. With pores of about 2.8 x 3.6 angstrom, the activated 1a exhibits exclusive adsorption of water over methanol in a binary water-methanol (1:1) liquid mixture.
引用
收藏
页码：5543 / 5545
页数：3
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