A Robust Highly Interpenetrated Metal-Organic Framework Constructed from Pentanuclear Clusters for Selective Sorption of Gas Molecules

被引：100
|
作者：
Zhang, Zhangjing [1 ]
Xiang, Shengchang [1 ]
Chen, Yu-Sheng [2 ]
Ma, Shengqian [2 ]
Lee, Yongwoo [3 ]
Phely-Bobin, Thomas [3 ]
Chen, Banglin [1 ]
机构：
[1] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[2] Univ Chicago, Ctr Adv Radiat Sources, ChemMatCARS, Argonne, IL 60439 USA
[3] QinetiQ N Amer, Technol Solut Grp, Waltham, MA 02451 USA
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 18期
基金：
美国国家科学基金会;
关键词：
ZEOLITIC IMIDAZOLATE FRAMEWORKS; POROUS COORDINATION-POLYMER; MICROPOROUS METAL; CARBON-DIOXIDE; KINETIC SEPARATION; THERMAL-STABILITY; CRYSTAL-STRUCTURE; PORE-SIZE; ADSORPTION; CO2;
D O I：
10.1021/ic1010083
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A three-dimensional microporous metal organic framework, Zn-5(BTA)(6)(TDA)(2)center dot 15DMF center dot 8H(2)O (1; HBTA = 1,2,3-benzenetriazole; H(2)TDA = thiophene-2,5-dicarboxylic acid), comprising pentanuclear [Zn-5]cluster units, was obtained through an one-pot solvothermal reaction of Zn(NO3)(2), 1,2,3-benzenetriazole, and thiophene-2,5-dicarboxylate. The activated 1 displays typed-I N-2 gas sorption behavior with a Langmuir surface area of 607 m(2) g(-1) and exhibits interesting selective gas adsorption for C2H2/CH4 and CO2/CH4.
引用
收藏
页码：8444 / 8448
页数：5
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