A robust microporous metal-organic framework constructed from a flexible organic linker for highly selective sorption of methanol over ethanol and water

被引：18

作者：

Huang, Qian ^{[1
]}

Cai, Jianfeng ^{[1
]}

Wu, Hui ^{[3
,4
]}

He, Yabing ^{[2
]}

Chen, Banglin ^{[1
,2
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, UTSA Circle 1, San Antonio, TX 78249 USA

[3] NIST, Ctr Neutron Res, Gaithersburg, MD 20899 USA

[4] Univ Maryland, Dept Mat Sci & Engn, College Pk, MD 20742 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2012年 / 22卷 / 20期

基金：

中国国家自然科学基金;

关键词：

INFINITE POLYMERIC FRAMEWORKS; RATIONALLY TUNED MICROPORES; CARBON-DIOXIDE CAPTURE; ROOM-TEMPERATURE; COORDINATION POLYMER; KINETIC SEPARATION; SMALL MOLECULES; GAS-ADSORPTION; SINGLE-CRYSTAL; CO2; UPTAKE;

D O I：

10.1039/c2jm15604k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A microporous metal-organic framework MOF 1 [Zn(L)(2)(methanol)(2)] (H2L (1R, 3S)-1,2,2-trimethyl- 3-(pyridin-4-ylcarbamoyl) cyclopentanecarboxylic acid) constructed from a flexible Zn2+ node and a flexible organic linker L was obtained by solvothermal reaction of diamond topology, and exhibits highly selective sorption of methanol over ethanol and water.

引用

页码：10352 / 10355

页数：4

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