A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules

被引：217
|
作者：
Chen, Banglin [1 ]
Ma, Shengqian
Hurtado, Eric J.
Lobkovsky, Emil B.
Zhou, Hong-Cai
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
[3] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 21期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1021/ic7014034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5)center dot xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 angstrom, the activated 1a exhibits highly selective sorption behavior toward H-2/N-2, H-2/CO, and CO2/CH4.
引用
收藏
页码：8490 / 8492
页数：3
相关论文
共 50 条
  • [1] A microporous metal-organic framework with butynelene functionality for selective gas sorption
    Wang, Lifeng
    Zhai, Lu
    Ren, Xiaoming
    Zhang, Wenwei
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2013, 204 : 53 - 58
  • [2] A Robust Highly Interpenetrated Metal-Organic Framework Constructed from Pentanuclear Clusters for Selective Sorption of Gas Molecules
    Zhang, Zhangjing
    Xiang, Shengchang
    Chen, Yu-Sheng
    Ma, Shengqian
    Lee, Yongwoo
    Phely-Bobin, Thomas
    Chen, Banglin
    [J]. INORGANIC CHEMISTRY, 2010, 49 (18) : 8444 - 8448
  • [3] A New Approach to Construct a Doubly Interpenetrated Microporous Metal-Organic Framework of Primitive Cubic Net for Highly Selective Sorption of Small Hydrocarbon Molecules
    Das, Madhab C.
    Xu, Hui
    Xiang, Shengchang
    Zhang, Zhangjing
    Arman, Hadi D.
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (28) : 7817 - 7822
  • [4] A partially interpenetrated metal-organic framework for selective hysteretic sorption of carbon dioxide
    Yang, Sihai
    Lin, Xiang
    Lewis, William
    Suyetin, Mikhail
    Bichoutskaia, Elena
    Parker, Julia E.
    Tang, Chiu C.
    Allan, David R.
    Rizkallah, Pierre J.
    Hubberstey, Peter
    Champness, Neil R.
    Thomas, K. Mark
    Blake, Alexander J.
    Schroeder, Martin
    [J]. NATURE MATERIALS, 2012, 11 (08) : 710 - 716
  • [5] A partially interpenetrated metal-organic framework for selective hysteretic sorption of carbon dioxide
    Yang S.
    Lin X.
    Lewis W.
    Suyetin M.
    Bichoutskaia E.
    Parker J.E.
    Tang C.C.
    Allan D.R.
    Rizkallah P.J.
    Hubberstey P.
    Champness N.R.
    Mark Thomas K.
    Blake A.J.
    Schröder M.
    [J]. Nature Materials, 2012, 11 (8) : 710 - 716
  • [6] Interpenetrated Metal-Organic Framework with Selective Gas Adsorption and Luminescent Properties
    Qin, Ling
    Ju, Ze-Min
    Wang, Zhong-Jie
    Meng, Fan-Dian
    Zheng, He-Gen
    Chen, Jin-Xi
    [J]. CRYSTAL GROWTH & DESIGN, 2014, 14 (06) : 2742 - 2746
  • [7] Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules
    Chen, Banglin
    Ma, Shengqian
    Zapata, Fatima
    Fronczek, Frank R.
    Lobkovsky, Emil B.
    Zhou, Hong-Cai
    [J]. INORGANIC CHEMISTRY, 2007, 46 (04) : 1233 - 1236
  • [8] Selective gas sorption within a dynamic metal-organic framework
    Chen, Banglin
    Ma, Shengqian
    Hurtado, Eric J.
    Lobkovsky, Emil B.
    Liang, Chengdu
    Zhu, Haoguo
    Dai, Sheng
    [J]. INORGANIC CHEMISTRY, 2007, 46 (21) : 8705 - 8709
  • [9] A microporous manganese-based metal-organic framework for gas sorption and separation
    Zhao, Ying-Ping
    Yang, Hui
    Wang, Fei
    Du, Zi-Yi
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2014, 1074 : 19 - 21
  • [10] A two dimensional microporous metal-organic framework for selective gas separation
    Alawisi, Hussah
    Li, Bin
    Alfooty, Khalid
    Wu, Ling
    Xiang, Shengchang
    Wang, Hailong
    Chen, Banglin
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2014, 50 : 106 - 109
12345