A triply interpenetrated microporous metal-organic framework for selective sorption of gas molecules

被引：217
|
作者：
Chen, Banglin [1 ]
Ma, Shengqian
Hurtado, Eric J.
Lobkovsky, Emil B.
Zhou, Hong-Cai
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA
[3] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 21期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1021/ic7014034
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5)center dot xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 angstrom, the activated 1a exhibits highly selective sorption behavior toward H-2/N-2, H-2/CO, and CO2/CH4.
引用
收藏
页码：8490 / 8492
页数：3
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