A microporous metal-organic framework for gas-chromatographic separation of alkanes

被引：1157
|
作者：
Chen, BL [1 ]
Liang, CD
Yang, J
Contreras, DS
Clancy, YL
Lobkovsky, EB
Yaghi, OM
Dai, S
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburg, TX 78541 USA
[2] Oak Ridge Natl Lab, Div Chem Sci, Oak Ridge, TN 37831 USA
[3] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
[4] Cornell Univ, Baker Lab, Dept Chem & Biol Chem, Ithaca, NY 14853 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 09期
关键词：
alkanes; gas chromatography; metal-organic frameworks; microporous materials; sorption;
D O I：
10.1002/anie.200502844
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) Filling the pores: A zinc-based metal-organic framework (MOF) can be transformed reversibly from an open (a) to a dense (b) configuration. The microporous solid is the first example of a MOF that is highly selective in the gas-chromatographic separation of alkanes. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1390 / 1393
页数：4
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