Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries

被引：121

作者：

Liu, Xu ^{[1
,2
]}

Zhang, Huang ^{[1
,2
]}

Geiger, Dorin ^{[3
]}

Han, Jin ^{[1
,2
]}

Varzi, Alberto ^{[1
,2
]}

Kaiser, Ute ^{[3
]}

Moretti, Arianna ^{[1
,2
]}

Passerini, Stefano ^{[1
,2
]}

机构：

[1] HIU, Electrochem 1, D-89081 Ulm, Germany

[2] KIT, D-76021 Karlsruhe, Germany

[3] Ulm Univ, Electron Microscopy Grp Mat Sci, Cent Facil Electron Microscopy, Albert Einstein Allee 11, D-89081 Ulm, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 16期

关键词：

STORAGE;

D O I：

10.1039/c8cc07243d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, CaV6O16 center dot 3H(2)O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 angstrom). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.

引用

页码：2265 / 2268

页数：4

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