Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries

被引：121
|
作者：
Liu, Xu [1 ,2 ]
Zhang, Huang [1 ,2 ]
Geiger, Dorin [3 ]
Han, Jin [1 ,2 ]
Varzi, Alberto [1 ,2 ]
Kaiser, Ute [3 ]
Moretti, Arianna [1 ,2 ]
Passerini, Stefano [1 ,2 ]
机构：
[1] HIU, Electrochem 1, D-89081 Ulm, Germany
[2] KIT, D-76021 Karlsruhe, Germany
[3] Ulm Univ, Electron Microscopy Grp Mat Sci, Cent Facil Electron Microscopy, Albert Einstein Allee 11, D-89081 Ulm, Germany
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 16期
关键词：
STORAGE;
D O I：
10.1039/c8cc07243d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
For the first time, CaV6O16 center dot 3H(2)O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 angstrom). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.
引用
收藏
页码：2265 / 2268
页数：4
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