Halogen Addition to a Frustrated Lewis Pair

被引：18
|
作者：
Froemel, Silke [1 ]
Froehlich, Roland [1 ]
Daniliuc, Constantin G. [1 ]
Kehr, Gerald [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 23期
关键词：
Frustrated Lewis pairs; Phosphorus; Boron; Halogens; Zwitterions; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; SOLID-STATE; CRYSTAL-STRUCTURES; REAGENT PH3PCL2; ALKYL CHLORIDES; BORANE; PHOSPHINES; ALCOHOLS; BIS(PENTAFLUOROPHENYL)BORANE;
D O I：
10.1002/ejic.201200288
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactive intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B(C6F5)2 reacts rapidly with thionyl chloride to yield the zwitterionic chlorination product [Mes2PCl+]CH2CH2[BCl(C6F5)2]. Analogous zwitterionic products were obtained by the reaction of the FLP with chlorine or bromine. Compounds [Mes2PX+]CH2CH2[BX(C6F5)2] (X = Cl, Br) were characterized by X-ray crystal structure analyses.
引用
收藏
页码：3774 / 3779
页数：6
相关论文
共 50 条
  • [31] Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction
    Moemming, Cornelia M.
    Froemel, Silke
    Kehr, Gerald
    Froehlich, Roland
    Grimme, Stefan
    Erker, Gerhard
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (34) : 12280 - 12289
  • [32] Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
    Lucile Chatelain
    Elisa Louyriac
    Iskander Douair
    Erli Lu
    Floriana Tuna
    Ashley J. Wooles
    Benedict M. Gardner
    Laurent Maron
    Stephen T. Liddle
    Nature Communications, 11
  • [33] Olefin-Borane "van der Waals Complexes": Intermediates in Frustrated Lewis Pair Addition Reactions
    Zhao, Xiaoxi
    Stephan, Douglas W.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (32) : 12448 - 12450
  • [34] Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair
    Moericke, Jennifer
    Wibbeling, Birgit
    Daniliuc, Constantin G.
    Kehr, Gerald
    Erker, Gerhard
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2101):
  • [35] Reversible Frustrated Lewis Pair Addition of N-Heterocycles to Unsaturated C-C Bonds
    Dornan, Peter K.
    Longobardi, Lauren E.
    Stephan, Douglas W.
    SYNLETT, 2014, 25 (11) : 1521 - 1524
  • [36] A Phosphanyl-Phosphagallene that Functions as a Frustrated Lewis Pair
    Wilson, Daniel W. N.
    Feld, Joey
    Goicoechea, Jose M.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (47) : 20914 - 20918
  • [37] New Insights in Frustrated Lewis Pair Chemistry with Azides
    Boom, Devin H. A.
    Jupp, Andrew R.
    Nieger, Martin
    Ehlers, Andreas W.
    Slootweg, J. Chris
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (58) : 13299 - 13308
  • [38] Frustrated Lewis Pair Reactions at the [3]Ferrocenophane Framework
    Unverhau, Kerstin
    Luebbe, Gerrit
    Wibbeling, Birgit
    Froehlich, Roland
    Kehr, Gerald
    Erker, Gerhard
    ORGANOMETALLICS, 2010, 29 (21) : 5320 - 5329
  • [39] Rheological Characterization of Polymeric Frustrated Lewis Pair Networks
    Yolsal, Utku
    Wang, Meng
    Royer, John R.
    Shaver, Michael P.
    MACROMOLECULES, 2019, 52 (09) : 3417 - 3425
  • [40] Frustrated Lewis pair behavior of a neutral scandium complex
    Chang, Kejian
    Xu, Xin
    DALTON TRANSACTIONS, 2017, 46 (14) : 4514 - 4517
12345