Frustrated Lewis pair behavior of a neutral scandium complex

被引：27
|
作者：
Chang, Kejian [1 ]
Xu, Xin [1 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China
来源：
DALTON TRANSACTIONS | 2017年 / 46卷 / 14期
基金：
中国国家自然科学基金;
关键词：
ZIRCONOCENE-PHOSPHINOARYLOXIDE COMPLEXES; LATE HETEROBIMETALLIC COMPLEXES; HETEROCYCLIC CARBENE COMPLEX; SMALL-MOLECULE ACTIVATION; FREE HYDROGEN ACTIVATION; CARBON-DIOXIDE; PHOSPHAZINE COMPLEXES; METAL; REACTIVITY; CATALYSIS;
D O I：
10.1039/c7dt00676d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An easily-accessible neutral scandium complex Sc[OC(CH3)(2)CH2PPh2] [O-2,6-tBu(2)-C6H3](2)[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.
引用
收藏
页码：4514 / 4517
页数：4
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