Halogen Addition to a Frustrated Lewis Pair

被引：18

作者：

Froemel, Silke ^{[1
]}

Froehlich, Roland ^{[1
]}

Daniliuc, Constantin G. ^{[1
]}

Kehr, Gerald ^{[1
]}

Erker, Gerhard ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 23期

关键词：

Frustrated Lewis pairs; Phosphorus; Boron; Halogens; Zwitterions; FREE CATALYTIC-HYDROGENATION; HETEROLYTIC DIHYDROGEN ACTIVATION; SOLID-STATE; CRYSTAL-STRUCTURES; REAGENT PH3PCL2; ALKYL CHLORIDES; BORANE; PHOSPHINES; ALCOHOLS; BIS(PENTAFLUOROPHENYL)BORANE;

D O I：

10.1002/ejic.201200288

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactive intramolecular frustrated Lewis pair (FLP) Mes2PCH2CH2B(C6F5)2 reacts rapidly with thionyl chloride to yield the zwitterionic chlorination product [Mes2PCl+]CH2CH2[BCl(C6F5)2]. Analogous zwitterionic products were obtained by the reaction of the FLP with chlorine or bromine. Compounds [Mes2PX+]CH2CH2[BX(C6F5)2] (X = Cl, Br) were characterized by X-ray crystal structure analyses.

引用

页码：3774 / 3779

页数：6

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