Synthesis of Manganese ZIF-8 from [Mn(BH4)2•3THF]•NaBH4

被引：42
|
作者：
Kadota, Kentaro [1 ]
Sivaniah, Easan [1 ,3 ]
Bureekaew, Sareeya [4 ]
Kitagawa, Susumu [3 ]
Horike, Satoshi [2 ,3 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[3] Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci WPI iCeMS, Kyoto 6068501, Japan
[4] Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Dept Chem & Biomol Engn, Rayong 21210, Thailand
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 15期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
METAL-ORGANIC FRAMEWORKS; IMIDAZOLATE FRAMEWORKS; CRYSTAL-STRUCTURES; THERMAL-STABILITY; SURFACE; COMPLEXES; CATALYSIS; DESIGN;
D O I：
10.1021/acs.inorgchem.7b01322
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cubic and highly porous [Mn(2-methyl-imidazolate)(2)] (Mn-ZIF-8) was synthesized from [Mn-(BH4)(2)center dot 3THF]center dot NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)(2)]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal organic framework systems.
引用
收藏
页码：8744 / 8747
页数：4
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