Synthesis of magnesium ZIF-8 from Mg(BH4)2

被引：33
|
作者：
Horike, S. [1 ,2 ]
Kadota, K. [1 ]
Itakura, T. [3 ]
Inukai, M. [4 ]
Kitagawa, S. [1 ,4 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan
[3] DENSO Corp, Kariya, Aichi 4488661, Japan
[4] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan
来源：
DALTON TRANSACTIONS | 2015年 / 44卷 / 34期
基金：
日本科学技术振兴机构;
关键词：
METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; THERMAL-STABILITY; SURFACE-AREA; COMPLEX;
D O I：
10.1039/c5dt01183c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Porous Mg(2-methyl imidazolate)(2) (Mg-ZIF-8) was synthesised from Mg(BH4)(2) as a precursor under an Ar atmosphere. It possesses an uncommon tetrahedral Mg2+-N coordination geometry that is stabilised by the formation of a framework, and it exhibits a Brunauer-Emmett-Teller surface area greater than 1800 m(2) g(-1).
引用
收藏
页码：15107 / 15110
页数：4
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